Rhodium-Catalyzed Defluorinative Vinylation of gem-Difluoroalkenes for the Synthesis of 2-Fluoro-1,3-dienes

Keyphrases

• Rhodium Catalysis 100%
• Defluorinative 100%
• Gem-difluoroalkenes 100%
• Fluoro 100%
• Vinylation 100%
• 1,3-dienes 100%
• Mechanistic Studies 33%
• Unique Effects 33%
• Good Yield 33%
• Halides 33%
• Stereoselectivity 33%
• Cross-coupling 33%
• Rh(III)-catalyzed 33%
• Bond Activation 33%
• Acrylamide 33%
• Nucleophilic Addition 33%
• C(sp2)-H Bond 33%
• Fluorine Substitution 33%
• Reaction Profile 33%

Chemistry

• Rhodium 100%
• vinylation 100%
• Halide 50%
• formation 50%
• Stereoselectivity 50%
• Mechanistic Study 50%
• Hydrogen Bond 50%
• Fluorine 50%
• Nucleophilic Addition 50%
• Acrylamide 50%