3D lanthanide coordination polymers constructed from polynuclear clusters and V-shaped organic connectors: Syntheses, structures and properties

Shengyan Wang; Jianing Xu; Liang Shan; Li Wang; Tianyou Song; Chenghui Zhang; Xiaodong Chen; Yong Fan

doi:10.1016/j.ica.2014.11.040

3D lanthanide coordination polymers constructed from polynuclear clusters and V-shaped organic connectors: Syntheses, structures and properties

Shengyan Wang, Jianing Xu, Liang Shan, Li Wang^*, Tianyou Song, Chenghui Zhang, Xiaodong Chen, Yong Fan

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Two novel lanthanide coordination polymers (Ln-CPs), [Ln₁₁(OH)₈(4,4′-oba)₁₂(CH₃COO)₂]·(CH₃)₂NH₂·3DMF·nH₂O, (Ln = Yb(1), Er(2), 4,4′-H₂oba = 4,4′-oxybis(benzoic acid), DMF = N, N′-dimethylformamide, n = 2 for 1, 3 for 2) have been self-assembled from the reaction of hexanuclear lanthanide complexes with flexible V-shaped organic ligands under solvothermal condition. Structural analyses reveal that they are isomorphous and feature a complicated three-dimensional (3D) framework containing novel octanuclear [Ln₈(OH)₈]¹⁶⁺ units. Moreover, they show the characteristic luminescence emission bands of the corresponding lanthanide ions in the near-infrared regions in the solid-state. Additionally, magnetic property of 1 shows typical antiferromagnetic interactions.

Original language	English
Pages (from-to)	118-123
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	427
DOIs	https://doi.org/10.1016/j.ica.2014.11.040
Publication status	Published - Mar 1 2015
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2014 Elsevier B.V. All rights reserved.

ASJC Scopus Subject Areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Keywords

Coordination polymer
Lanthanide
Luminescence
Magnetism
Polynuclear cluster

Access to Document

10.1016/j.ica.2014.11.040

Cite this

@article{44f95151f8d64704861a311899cf3949,

title = "3D lanthanide coordination polymers constructed from polynuclear clusters and V-shaped organic connectors: Syntheses, structures and properties",

abstract = "Two novel lanthanide coordination polymers (Ln-CPs), [Ln11(OH)8(4,4′-oba)12(CH3COO)2]·(CH3)2NH2·3DMF·nH2O, (Ln = Yb(1), Er(2), 4,4′-H2oba = 4,4′-oxybis(benzoic acid), DMF = N, N′-dimethylformamide, n = 2 for 1, 3 for 2) have been self-assembled from the reaction of hexanuclear lanthanide complexes with flexible V-shaped organic ligands under solvothermal condition. Structural analyses reveal that they are isomorphous and feature a complicated three-dimensional (3D) framework containing novel octanuclear [Ln8(OH)8]16+ units. Moreover, they show the characteristic luminescence emission bands of the corresponding lanthanide ions in the near-infrared regions in the solid-state. Additionally, magnetic property of 1 shows typical antiferromagnetic interactions.",

keywords = "Coordination polymer, Lanthanide, Luminescence, Magnetism, Polynuclear cluster",

author = "Shengyan Wang and Jianing Xu and Liang Shan and Li Wang and Tianyou Song and Chenghui Zhang and Xiaodong Chen and Yong Fan",

year = "2015",

month = mar,

day = "1",

doi = "10.1016/j.ica.2014.11.040",

language = "English",

volume = "427",

pages = "118--123",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier BV",

}

TY - JOUR

T1 - 3D lanthanide coordination polymers constructed from polynuclear clusters and V-shaped organic connectors

T2 - Syntheses, structures and properties

AU - Wang, Shengyan

AU - Xu, Jianing

AU - Shan, Liang

AU - Wang, Li

AU - Song, Tianyou

AU - Zhang, Chenghui

AU - Chen, Xiaodong

AU - Fan, Yong

PY - 2015/3/1

Y1 - 2015/3/1

N2 - Two novel lanthanide coordination polymers (Ln-CPs), [Ln11(OH)8(4,4′-oba)12(CH3COO)2]·(CH3)2NH2·3DMF·nH2O, (Ln = Yb(1), Er(2), 4,4′-H2oba = 4,4′-oxybis(benzoic acid), DMF = N, N′-dimethylformamide, n = 2 for 1, 3 for 2) have been self-assembled from the reaction of hexanuclear lanthanide complexes with flexible V-shaped organic ligands under solvothermal condition. Structural analyses reveal that they are isomorphous and feature a complicated three-dimensional (3D) framework containing novel octanuclear [Ln8(OH)8]16+ units. Moreover, they show the characteristic luminescence emission bands of the corresponding lanthanide ions in the near-infrared regions in the solid-state. Additionally, magnetic property of 1 shows typical antiferromagnetic interactions.

AB - Two novel lanthanide coordination polymers (Ln-CPs), [Ln11(OH)8(4,4′-oba)12(CH3COO)2]·(CH3)2NH2·3DMF·nH2O, (Ln = Yb(1), Er(2), 4,4′-H2oba = 4,4′-oxybis(benzoic acid), DMF = N, N′-dimethylformamide, n = 2 for 1, 3 for 2) have been self-assembled from the reaction of hexanuclear lanthanide complexes with flexible V-shaped organic ligands under solvothermal condition. Structural analyses reveal that they are isomorphous and feature a complicated three-dimensional (3D) framework containing novel octanuclear [Ln8(OH)8]16+ units. Moreover, they show the characteristic luminescence emission bands of the corresponding lanthanide ions in the near-infrared regions in the solid-state. Additionally, magnetic property of 1 shows typical antiferromagnetic interactions.

KW - Coordination polymer

KW - Lanthanide

KW - Luminescence

KW - Magnetism

KW - Polynuclear cluster

UR - http://www.scopus.com/inward/record.url?scp=84920148556&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84920148556&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2014.11.040

DO - 10.1016/j.ica.2014.11.040

M3 - Article

AN - SCOPUS:84920148556

SN - 0020-1693

VL - 427

SP - 118

EP - 123

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

3D lanthanide coordination polymers constructed from polynuclear clusters and V-shaped organic connectors: Syntheses, structures and properties

Abstract

Bibliographical note

ASJC Scopus Subject Areas

Keywords

Access to Document

Other files and links

Fingerprint

Cite this