3D lanthanide metal-organic frameworks constructed from 2,6-naphthalenedicarboxylate ligand: synthesis, structure, luminescence and dye adsorption

Yajing Zhu; Li Wang; Xiaodong Chen; Pengcheng Wang; Yong Fan; Ping Zhang

doi:10.1016/j.jssc.2017.04.026

3D lanthanide metal-organic frameworks constructed from 2,6-naphthalenedicarboxylate ligand: synthesis, structure, luminescence and dye adsorption

Yajing Zhu, Li Wang, Xiaodong Chen, Pengcheng Wang, Yong Fan, Ping Zhang^*

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

A series of novel isostructural 3D lanthanide metal-organic frameworks {[Ln₂(NDC)₃(H₂O)₄]·(DMF)₄}_n (Ln=Eu(1), Gd(2), Tb(3), Er(4), Yb(5), Dy(6), Y(7), Lu(8), H₂NDC =2,6-Naphthalenedicarboxylic acid, DMF=N,N-dimethylformamide) with a rhombic channel along the b axis and high thermal stabilities, have been successfully synthesized under solvothermal conditions. The network can be described as 2, 4, 5-connected net with Schäfli symbol of (4².6².8²)₂(4².6³.8⁵)₂(6). Luminescent studies illustrate that 1, 2, 7 and 8 exhibit strong luminescent emitting of the corresponding Ln(III) centers in the visible range, while 5 shows near-infrared range (NIR) luminescence. Further studies of 1 and 2A (activated product of 2) show that 1 displays good stability in different solvents and excellent fluorescence sensing for organic solvent small molecules and 2A ([Gd₂(NDC)₃(H₂O)₄]_n) exhibits good adsorption capacity for organic dyes in water, especially for crystal violet.

Original language	English
Pages (from-to)	248-254
Number of pages	7
Journal	Journal of Solid State Chemistry
Volume	251
DOIs	https://doi.org/10.1016/j.jssc.2017.04.026
Publication status	Published - Jul 1 2017
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2017

ASJC Scopus Subject Areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Keywords

Dye absorption
Ln-MOF
Luminescence
NIR

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10.1016/j.jssc.2017.04.026

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title = "3D lanthanide metal-organic frameworks constructed from 2,6-naphthalenedicarboxylate ligand: synthesis, structure, luminescence and dye adsorption",

abstract = "A series of novel isostructural 3D lanthanide metal-organic frameworks {[Ln2(NDC)3(H2O)4]·(DMF)4}n (Ln=Eu(1), Gd(2), Tb(3), Er(4), Yb(5), Dy(6), Y(7), Lu(8), H2NDC =2,6-Naphthalenedicarboxylic acid, DMF=N,N-dimethylformamide) with a rhombic channel along the b axis and high thermal stabilities, have been successfully synthesized under solvothermal conditions. The network can be described as 2, 4, 5-connected net with Sch{\"a}fli symbol of (42.62.82)2(42.63.85)2(6). Luminescent studies illustrate that 1, 2, 7 and 8 exhibit strong luminescent emitting of the corresponding Ln(III) centers in the visible range, while 5 shows near-infrared range (NIR) luminescence. Further studies of 1 and 2A (activated product of 2) show that 1 displays good stability in different solvents and excellent fluorescence sensing for organic solvent small molecules and 2A ([Gd2(NDC)3(H2O)4]n) exhibits good adsorption capacity for organic dyes in water, especially for crystal violet.",

keywords = "Dye absorption, Ln-MOF, Luminescence, NIR",

author = "Yajing Zhu and Li Wang and Xiaodong Chen and Pengcheng Wang and Yong Fan and Ping Zhang",

note = "Publisher Copyright: {\textcopyright} 2017",

year = "2017",

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doi = "10.1016/j.jssc.2017.04.026",

language = "English",

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T1 - 3D lanthanide metal-organic frameworks constructed from 2,6-naphthalenedicarboxylate ligand

T2 - synthesis, structure, luminescence and dye adsorption

AU - Zhu, Yajing

AU - Wang, Li

AU - Chen, Xiaodong

AU - Wang, Pengcheng

AU - Fan, Yong

AU - Zhang, Ping

PY - 2017/7/1

Y1 - 2017/7/1

N2 - A series of novel isostructural 3D lanthanide metal-organic frameworks {[Ln2(NDC)3(H2O)4]·(DMF)4}n (Ln=Eu(1), Gd(2), Tb(3), Er(4), Yb(5), Dy(6), Y(7), Lu(8), H2NDC =2,6-Naphthalenedicarboxylic acid, DMF=N,N-dimethylformamide) with a rhombic channel along the b axis and high thermal stabilities, have been successfully synthesized under solvothermal conditions. The network can be described as 2, 4, 5-connected net with Schäfli symbol of (42.62.82)2(42.63.85)2(6). Luminescent studies illustrate that 1, 2, 7 and 8 exhibit strong luminescent emitting of the corresponding Ln(III) centers in the visible range, while 5 shows near-infrared range (NIR) luminescence. Further studies of 1 and 2A (activated product of 2) show that 1 displays good stability in different solvents and excellent fluorescence sensing for organic solvent small molecules and 2A ([Gd2(NDC)3(H2O)4]n) exhibits good adsorption capacity for organic dyes in water, especially for crystal violet.

AB - A series of novel isostructural 3D lanthanide metal-organic frameworks {[Ln2(NDC)3(H2O)4]·(DMF)4}n (Ln=Eu(1), Gd(2), Tb(3), Er(4), Yb(5), Dy(6), Y(7), Lu(8), H2NDC =2,6-Naphthalenedicarboxylic acid, DMF=N,N-dimethylformamide) with a rhombic channel along the b axis and high thermal stabilities, have been successfully synthesized under solvothermal conditions. The network can be described as 2, 4, 5-connected net with Schäfli symbol of (42.62.82)2(42.63.85)2(6). Luminescent studies illustrate that 1, 2, 7 and 8 exhibit strong luminescent emitting of the corresponding Ln(III) centers in the visible range, while 5 shows near-infrared range (NIR) luminescence. Further studies of 1 and 2A (activated product of 2) show that 1 displays good stability in different solvents and excellent fluorescence sensing for organic solvent small molecules and 2A ([Gd2(NDC)3(H2O)4]n) exhibits good adsorption capacity for organic dyes in water, especially for crystal violet.

KW - Dye absorption

KW - Ln-MOF

KW - Luminescence

KW - NIR

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3D lanthanide metal-organic frameworks constructed from 2,6-naphthalenedicarboxylate ligand: synthesis, structure, luminescence and dye adsorption

Abstract

Bibliographical note

ASJC Scopus Subject Areas

Keywords

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