A convenient synthesis of Os3(CO)12 from OsO4 and formic acid

Elumalai Kumaran; Weng Kee Leong

doi:10.1016/j.jorganchem.2024.123480

A convenient synthesis of Os₃(CO)₁₂ from OsO₄ and formic acid

Elumalai Kumaran, Weng Kee Leong^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Short survey › peer-review

Abstract

A convenient synthesis of the osmium carbonyl cluster Os₃(CO)₁₂ starting from osmium tetroxide and the in-situ generation of gaseous carbon monoxide via the decomposition of formic acid, is reported.

Original language	English
Article number	123480
Journal	Journal of Organometallic Chemistry
Volume	1025
DOIs	https://doi.org/10.1016/j.jorganchem.2024.123480
Publication status	Published - Feb 1 2025
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2024

ASJC Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Keywords

Carbon monoxide
Carbonyl cluster
Formic acid
Osmium
Synthesis

Access to Document

10.1016/j.jorganchem.2024.123480

Cite this

@article{b88b0e3236e441a489cab546375531f3,

title = "A convenient synthesis of Os3(CO)12 from OsO4 and formic acid",

abstract = "A convenient synthesis of the osmium carbonyl cluster Os3(CO)12 starting from osmium tetroxide and the in-situ generation of gaseous carbon monoxide via the decomposition of formic acid, is reported.",

keywords = "Carbon monoxide, Carbonyl cluster, Formic acid, Osmium, Synthesis",

author = "Elumalai Kumaran and Leong, {Weng Kee}",

note = "Publisher Copyright: {\textcopyright} 2024",

year = "2025",

month = feb,

day = "1",

doi = "10.1016/j.jorganchem.2024.123480",

language = "English",

volume = "1025",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

}

TY - JOUR

T1 - A convenient synthesis of Os3(CO)12 from OsO4 and formic acid

AU - Kumaran, Elumalai

AU - Leong, Weng Kee

PY - 2025/2/1

Y1 - 2025/2/1

N2 - A convenient synthesis of the osmium carbonyl cluster Os3(CO)12 starting from osmium tetroxide and the in-situ generation of gaseous carbon monoxide via the decomposition of formic acid, is reported.

AB - A convenient synthesis of the osmium carbonyl cluster Os3(CO)12 starting from osmium tetroxide and the in-situ generation of gaseous carbon monoxide via the decomposition of formic acid, is reported.

KW - Carbon monoxide

KW - Carbonyl cluster

KW - Formic acid

KW - Osmium

KW - Synthesis

UR - http://www.scopus.com/inward/record.url?scp=85212434532&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85212434532&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2024.123480

DO - 10.1016/j.jorganchem.2024.123480

M3 - Short survey

AN - SCOPUS:85212434532

SN - 0022-328X

VL - 1025

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

M1 - 123480

ER -