TY - JOUR
T1 - A Mesoporous Zirconium-Isophthalate Multifunctional Platform
AU - Wang, Sujing
AU - Chen, Liyu
AU - Wahiduzzaman, Mohammad
AU - Tissot, Antoine
AU - Zhou, Lin
AU - Ibarra, Ilich A.
AU - Gutiérrez-Alejandre, Aída
AU - Lee, Ji Sun
AU - Chang, Jong San
AU - Liu, Zheng
AU - Marrot, Jérôme
AU - Shepard, William
AU - Maurin, Guillaume
AU - Xu, Qiang
AU - Serre, Christian
N1 - Publisher Copyright:
© 2020 Elsevier Inc.
PY - 2021/1/6
Y1 - 2021/1/6
N2 - Mesoporous materials suffer from poor crystallinity and hydrolytic stability, lack of chemical diversity, insufficient pore accessibility, complex synthesis, and toxicity issues. Here the association of Zr-oxo clusters and isophthalate via a homometallic-multicluster-dot strategy results in a robust mesoporous metal-organic framework, denoted as MIP-206 (MIP stands for materials of the Institute of Porous Materials of Paris), that overcomes the aforementioned limitations. MIP-206, with a combination of Zr6 and Zr12 oxo-cluster inorganic building units into a single structure, exhibits meso-channels of ca. 2.6 nm and displays excellent chemical stability. Owing to the abundant variety of functionalized isophthalic acid linkers, the chemical environment of MIP-206 can be tuned without hampering pore accessibility. MIP-206 loaded with palladium nanoparticles acts as an efficient and durable catalyst for the dehydrogenation of formic acid, outperforming benchmark mesoporous materials. This paves the way toward the utilization of MIP-206 as a mesoporous platform for a wide range of potential applications.
AB - Mesoporous materials suffer from poor crystallinity and hydrolytic stability, lack of chemical diversity, insufficient pore accessibility, complex synthesis, and toxicity issues. Here the association of Zr-oxo clusters and isophthalate via a homometallic-multicluster-dot strategy results in a robust mesoporous metal-organic framework, denoted as MIP-206 (MIP stands for materials of the Institute of Porous Materials of Paris), that overcomes the aforementioned limitations. MIP-206, with a combination of Zr6 and Zr12 oxo-cluster inorganic building units into a single structure, exhibits meso-channels of ca. 2.6 nm and displays excellent chemical stability. Owing to the abundant variety of functionalized isophthalic acid linkers, the chemical environment of MIP-206 can be tuned without hampering pore accessibility. MIP-206 loaded with palladium nanoparticles acts as an efficient and durable catalyst for the dehydrogenation of formic acid, outperforming benchmark mesoporous materials. This paves the way toward the utilization of MIP-206 as a mesoporous platform for a wide range of potential applications.
KW - feedstock isophthalic acid linker
KW - green chemistry
KW - HMD
KW - homometallic multicluster dot
KW - MAP1: Discovery
KW - metal-organic framework
KW - MOF
KW - nontoxic zirconium mesoporous MOF series
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U2 - 10.1016/j.matt.2020.10.009
DO - 10.1016/j.matt.2020.10.009
M3 - Article
AN - SCOPUS:85097051115
SN - 2590-2393
VL - 4
SP - 182
EP - 194
JO - Matter
JF - Matter
IS - 1
ER -