A Rare Earth Metal Catalyzed Aerobic Dehydrogenation of N-Heterocycles

Ting Zhang; Yongheng Lv; Zhenguo Zhang; Zhenhua Jia; Teck Peng Loh

doi:10.1021/acs.orglett.3c01449

A Rare Earth Metal Catalyzed Aerobic Dehydrogenation of N-Heterocycles

Ting Zhang, Yongheng Lv, Zhenguo Zhang, Zhenhua Jia^*, Teck Peng Loh^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Rare earth metals exhibit high catalytic activity and selectivity in various organic reactions due to their unique electronic properties. Among them, praseodymium has shown high catalytic activity under mild reaction conditions compared with transitional metals. Here, we report a strategy of Pr-catalyzed aerobic dehydrogenative aromatization of saturated N-heterocycles to produce 7 classes of products with a broad substrate scope.

Original language	English
Pages (from-to)	4468-4472
Number of pages	5
Journal	Organic Letters
Volume	25
Issue number	24
DOIs	https://doi.org/10.1021/acs.orglett.3c01449
Publication status	Published - Jun 23 2023
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2023 American Chemical Society.

ASJC Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/acs.orglett.3c01449

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abstract = "Rare earth metals exhibit high catalytic activity and selectivity in various organic reactions due to their unique electronic properties. Among them, praseodymium has shown high catalytic activity under mild reaction conditions compared with transitional metals. Here, we report a strategy of Pr-catalyzed aerobic dehydrogenative aromatization of saturated N-heterocycles to produce 7 classes of products with a broad substrate scope.",

author = "Ting Zhang and Yongheng Lv and Zhenguo Zhang and Zhenhua Jia and Loh, {Teck Peng}",

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AU - Zhang, Ting

AU - Lv, Yongheng

AU - Zhang, Zhenguo

AU - Jia, Zhenhua

AU - Loh, Teck Peng

PY - 2023/6/23

Y1 - 2023/6/23

N2 - Rare earth metals exhibit high catalytic activity and selectivity in various organic reactions due to their unique electronic properties. Among them, praseodymium has shown high catalytic activity under mild reaction conditions compared with transitional metals. Here, we report a strategy of Pr-catalyzed aerobic dehydrogenative aromatization of saturated N-heterocycles to produce 7 classes of products with a broad substrate scope.

AB - Rare earth metals exhibit high catalytic activity and selectivity in various organic reactions due to their unique electronic properties. Among them, praseodymium has shown high catalytic activity under mild reaction conditions compared with transitional metals. Here, we report a strategy of Pr-catalyzed aerobic dehydrogenative aromatization of saturated N-heterocycles to produce 7 classes of products with a broad substrate scope.

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A Rare Earth Metal Catalyzed Aerobic Dehydrogenation of N-Heterocycles

Abstract

Bibliographical note

ASJC Scopus Subject Areas

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