TY - JOUR
T1 - Acoustic shock wave-induced sp2-to-sp3-type phase transition
T2 - a case study of a graphite single crystal
AU - Aswathappa, Sivakumar
AU - Dai, Lidong
AU - Redfern, Simon A.T.
AU - Sahaya Jude Dhas, S.
AU - Feng, Xiaolei
AU - Palaniyasan, Eniya
AU - Kumar, Raju Suresh
N1 - Publisher Copyright:
© 2024 The Royal Society of Chemistry.
PY - 2024
Y1 - 2024
N2 - Achieving facile and simple temperature- and pressure-induced transformation of sp2-to-sp3 remains an important and fascinating challenge within the realm of carbon science and technology. Here, we introduce a new technique that utilizes repeated exposure of low-pressure (2.0 MPa) millisecond acoustic shock waves on a sample to facilitate the successful transformation of sp2-to-sp3 carbon bonds. This transformation is verified through visible Raman spectroscopic, X-ray photoelectron spectroscopic (XPS), and high-resolution transmission electron microscopic (HRTEM) observations. Typically, in general nanosecond dynamic compression experiments, sp3 carbon bond formation occurs only at pressures of ∼45 GPa or more, and under static compression, this transition takes place at ∼30 GPa. However, with our innovative approach, similar results can be achieved with acoustic shock waves operating at significantly lower pressures of 2.0 MPa. Based on the observed analytical results, the sp2-to-sp3 type phase transition occurred at the 500-shocked condition and this transition leads to the conversion of layered crystalline graphite to non-layered amorphous graphite, which may be the pre-state of sp3 bonded diamond formation. The complete disappearance of the 2D band in the Raman spectrum and the conversion of asymmetric to symmetric shape of the C 1s band in the XPS spectrum are the major proof for the proposed sp2-to-sp3 phase transition. Further optimization is currently underway to find the critical point in achieving the probable phase transition of graphite to diamond. The proposed technique put forward a platform for a new impending way to make the sp3 carbons from sp2 carbons in indoor laboratories, which may also offer a new science division to understand the formation of diamonds or diamond-like structures under lower transient pressure conditions. Even though the proposed technique is cost-effective and involves a handy tool, to move it from lab to industrial applications, we still have a lot of ground to cover in fundamental aspects.
AB - Achieving facile and simple temperature- and pressure-induced transformation of sp2-to-sp3 remains an important and fascinating challenge within the realm of carbon science and technology. Here, we introduce a new technique that utilizes repeated exposure of low-pressure (2.0 MPa) millisecond acoustic shock waves on a sample to facilitate the successful transformation of sp2-to-sp3 carbon bonds. This transformation is verified through visible Raman spectroscopic, X-ray photoelectron spectroscopic (XPS), and high-resolution transmission electron microscopic (HRTEM) observations. Typically, in general nanosecond dynamic compression experiments, sp3 carbon bond formation occurs only at pressures of ∼45 GPa or more, and under static compression, this transition takes place at ∼30 GPa. However, with our innovative approach, similar results can be achieved with acoustic shock waves operating at significantly lower pressures of 2.0 MPa. Based on the observed analytical results, the sp2-to-sp3 type phase transition occurred at the 500-shocked condition and this transition leads to the conversion of layered crystalline graphite to non-layered amorphous graphite, which may be the pre-state of sp3 bonded diamond formation. The complete disappearance of the 2D band in the Raman spectrum and the conversion of asymmetric to symmetric shape of the C 1s band in the XPS spectrum are the major proof for the proposed sp2-to-sp3 phase transition. Further optimization is currently underway to find the critical point in achieving the probable phase transition of graphite to diamond. The proposed technique put forward a platform for a new impending way to make the sp3 carbons from sp2 carbons in indoor laboratories, which may also offer a new science division to understand the formation of diamonds or diamond-like structures under lower transient pressure conditions. Even though the proposed technique is cost-effective and involves a handy tool, to move it from lab to industrial applications, we still have a lot of ground to cover in fundamental aspects.
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U2 - 10.1039/d4tc03216k
DO - 10.1039/d4tc03216k
M3 - Article
AN - SCOPUS:85201865916
SN - 2050-7526
JO - Journal of Materials Chemistry C
JF - Journal of Materials Chemistry C
ER -