Activation of dihydrogen by 1,4,2,5-diazadiborinine

Baolin Wang; Rei Kinjo

doi:10.1016/j.tet.2018.10.067

Activation of dihydrogen by 1,4,2,5-diazadiborinine

Baolin Wang, Rei Kinjo^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Activation of dihydrogen (H₂) by 1,4,2,5-diazadiborinine is reported. Under the heating condition, treatment of 1,4,2,5-diazadiborinine with H₂ results in the cleavage of H–H bond, to afford product 2, which was fully characterized by NMR and IR spectroscopy as well as X-ray diffraction and HRMS analysis. In the presence of borane dimethylsulfide complex (BH₃·SMe₂), 2 readily isomerizes to 3 under the mild reaction condition.

Original language	English
Pages (from-to)	7273-7276
Number of pages	4
Journal	Tetrahedron
Volume	74
Issue number	51
DOIs	https://doi.org/10.1016/j.tet.2018.10.067
Publication status	Published - Dec 20 2018
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2018 Elsevier Ltd

ASJC Scopus Subject Areas

Biochemistry
Drug Discovery
Organic Chemistry

Keywords

1,4,2,5-Diazadiborinine
Dihydrogen activation
Main group chemistry

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10.1016/j.tet.2018.10.067

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title = "Activation of dihydrogen by 1,4,2,5-diazadiborinine",

abstract = "Activation of dihydrogen (H2) by 1,4,2,5-diazadiborinine is reported. Under the heating condition, treatment of 1,4,2,5-diazadiborinine with H2 results in the cleavage of H–H bond, to afford product 2, which was fully characterized by NMR and IR spectroscopy as well as X-ray diffraction and HRMS analysis. In the presence of borane dimethylsulfide complex (BH3·SMe2), 2 readily isomerizes to 3 under the mild reaction condition.",

keywords = "1,4,2,5-Diazadiborinine, Dihydrogen activation, Main group chemistry",

author = "Baolin Wang and Rei Kinjo",

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year = "2018",

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day = "20",

doi = "10.1016/j.tet.2018.10.067",

language = "English",

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T1 - Activation of dihydrogen by 1,4,2,5-diazadiborinine

AU - Wang, Baolin

AU - Kinjo, Rei

PY - 2018/12/20

Y1 - 2018/12/20

N2 - Activation of dihydrogen (H2) by 1,4,2,5-diazadiborinine is reported. Under the heating condition, treatment of 1,4,2,5-diazadiborinine with H2 results in the cleavage of H–H bond, to afford product 2, which was fully characterized by NMR and IR spectroscopy as well as X-ray diffraction and HRMS analysis. In the presence of borane dimethylsulfide complex (BH3·SMe2), 2 readily isomerizes to 3 under the mild reaction condition.

AB - Activation of dihydrogen (H2) by 1,4,2,5-diazadiborinine is reported. Under the heating condition, treatment of 1,4,2,5-diazadiborinine with H2 results in the cleavage of H–H bond, to afford product 2, which was fully characterized by NMR and IR spectroscopy as well as X-ray diffraction and HRMS analysis. In the presence of borane dimethylsulfide complex (BH3·SMe2), 2 readily isomerizes to 3 under the mild reaction condition.

KW - 1,4,2,5-Diazadiborinine

KW - Dihydrogen activation

KW - Main group chemistry

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DO - 10.1016/j.tet.2018.10.067

M3 - Article

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VL - 74

SP - 7273

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JO - Tetrahedron

JF - Tetrahedron

IS - 51

ER -

Activation of dihydrogen by 1,4,2,5-diazadiborinine

Abstract

Bibliographical note

ASJC Scopus Subject Areas

Keywords

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