Acylation-cyclization of allenes

Roderick W. Bates; Thota Rama-Devi; Huei Huei Ko

doi:10.1016/0040-4020(95)00816-Q

Acylation-cyclization of allenes

Roderick W. Bates^*, Thota Rama-Devi, Huei Huei Ko

^*Corresponding author for this work

University of North Texas

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Allenes bearing a nucleophilic group cyclize on treatment with acyltetracarbonyl cobalt complexes in the presence of mild bases. Various nucleophilic groups and cobalt complexes can be used to give highly functionalized pyrrolidines, cyclopentanes and tetrahydrofurans. Disubstituted allenes may be used in the reaction. 1,3-disubstituted allenes give products with high stereoselectivity.

Original language	English
Pages (from-to)	12939-12954
Number of pages	16
Journal	Tetrahedron
Volume	51
Issue number	47
DOIs	https://doi.org/10.1016/0040-4020(95)00816-Q
Publication status	Published - Nov 20 1995
Externally published	Yes

ASJC Scopus Subject Areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/0040-4020(95)00816-Q

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title = "Acylation-cyclization of allenes",

abstract = "Allenes bearing a nucleophilic group cyclize on treatment with acyltetracarbonyl cobalt complexes in the presence of mild bases. Various nucleophilic groups and cobalt complexes can be used to give highly functionalized pyrrolidines, cyclopentanes and tetrahydrofurans. Disubstituted allenes may be used in the reaction. 1,3-disubstituted allenes give products with high stereoselectivity.",

author = "Bates, {Roderick W.} and Thota Rama-Devi and Ko, {Huei Huei}",

year = "1995",

month = nov,

day = "20",

doi = "10.1016/0040-4020(95)00816-Q",

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journal = "Tetrahedron",

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T1 - Acylation-cyclization of allenes

AU - Bates, Roderick W.

AU - Rama-Devi, Thota

AU - Ko, Huei Huei

PY - 1995/11/20

Y1 - 1995/11/20

N2 - Allenes bearing a nucleophilic group cyclize on treatment with acyltetracarbonyl cobalt complexes in the presence of mild bases. Various nucleophilic groups and cobalt complexes can be used to give highly functionalized pyrrolidines, cyclopentanes and tetrahydrofurans. Disubstituted allenes may be used in the reaction. 1,3-disubstituted allenes give products with high stereoselectivity.

AB - Allenes bearing a nucleophilic group cyclize on treatment with acyltetracarbonyl cobalt complexes in the presence of mild bases. Various nucleophilic groups and cobalt complexes can be used to give highly functionalized pyrrolidines, cyclopentanes and tetrahydrofurans. Disubstituted allenes may be used in the reaction. 1,3-disubstituted allenes give products with high stereoselectivity.

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U2 - 10.1016/0040-4020(95)00816-Q

DO - 10.1016/0040-4020(95)00816-Q

M3 - Article

AN - SCOPUS:0028783925

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VL - 51

SP - 12939

EP - 12954

JO - Tetrahedron

JF - Tetrahedron

IS - 47

ER -

Acylation-cyclization of allenes

Abstract

ASJC Scopus Subject Areas

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