Allylation reactions of N,O-heterocycles

Roderick W. Bates; Chi H. Tang; Yuting Tan; Siti Nurhayati Binte Buang

doi:10.1055/s-0031-1290458

Allylation reactions of N,O-heterocycles

Roderick W. Bates^*, Chi H. Tang, Yuting Tan, Siti Nurhayati Binte Buang

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Iminium ions generated from isoxazolidines and tetrahydro-1,2-oxazines undergo allylation under Sakurai conditions. Allylated isoxazolidines are formed predominantly as the trans isomer, while oxazines are formed exclusively as the cis isomer.

Original language	English
Pages (from-to)	2266-2268
Number of pages	3
Journal	Synlett
Volume	23
Issue number	15
DOIs	https://doi.org/10.1055/s-0031-1290458
Publication status	Published - 2012
Externally published	Yes

ASJC Scopus Subject Areas

Organic Chemistry

Keywords

allylation
heterocycles
stereoselectivity

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10.1055/s-0031-1290458

Cite this

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title = "Allylation reactions of N,O-heterocycles",

abstract = "Iminium ions generated from isoxazolidines and tetrahydro-1,2-oxazines undergo allylation under Sakurai conditions. Allylated isoxazolidines are formed predominantly as the trans isomer, while oxazines are formed exclusively as the cis isomer.",

keywords = "allylation, heterocycles, stereoselectivity",

author = "Bates, {Roderick W.} and Tang, {Chi H.} and Yuting Tan and Buang, {Siti Nurhayati Binte}",

year = "2012",

doi = "10.1055/s-0031-1290458",

language = "English",

volume = "23",

pages = "2266--2268",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "15",

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TY - JOUR

T1 - Allylation reactions of N,O-heterocycles

AU - Bates, Roderick W.

AU - Tang, Chi H.

AU - Tan, Yuting

AU - Buang, Siti Nurhayati Binte

PY - 2012

Y1 - 2012

N2 - Iminium ions generated from isoxazolidines and tetrahydro-1,2-oxazines undergo allylation under Sakurai conditions. Allylated isoxazolidines are formed predominantly as the trans isomer, while oxazines are formed exclusively as the cis isomer.

AB - Iminium ions generated from isoxazolidines and tetrahydro-1,2-oxazines undergo allylation under Sakurai conditions. Allylated isoxazolidines are formed predominantly as the trans isomer, while oxazines are formed exclusively as the cis isomer.

KW - allylation

KW - heterocycles

KW - stereoselectivity

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U2 - 10.1055/s-0031-1290458

DO - 10.1055/s-0031-1290458

M3 - Article

AN - SCOPUS:84865049055

SN - 0936-5214

VL - 23

SP - 2266

EP - 2268

JO - Synlett

JF - Synlett

IS - 15

ER -

Allylation reactions of N,O-heterocycles

Abstract

ASJC Scopus Subject Areas

Keywords

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