Aluminium triflate-catalysed regioselective cycloisomerisation of non-activated unsaturated oximes

Xavier Chaminade; Shunsuke Chiba; Koichi Narasaka; Elisabet Dunach

doi:10.1016/j.tetlet.2008.02.070

Aluminium triflate-catalysed regioselective cycloisomerisation of non-activated unsaturated oximes

Xavier Chaminade, Shunsuke Chiba, Koichi Narasaka^*, Elisabet Dunach

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

A novel cycloisomerisation of oximes bearing non-activated C-C double bonds occurs in an Al(III)-catalysed reaction. This process leads to 5-, 6- and 7-membered ring oxygen and nitrogen-containing heterocycles in good yields.

Original language	English
Pages (from-to)	2384-2387
Number of pages	4
Journal	Tetrahedron Letters
Volume	49
Issue number	15
DOIs	https://doi.org/10.1016/j.tetlet.2008.02.070
Publication status	Published - Apr 7 2008
Externally published	Yes

ASJC Scopus Subject Areas

Biochemistry
Drug Discovery
Organic Chemistry

Keywords

Aluminium trifluoromethansulfonate
Cycloisomerisation
Oxazepine
Oxazine
Oxime

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10.1016/j.tetlet.2008.02.070

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title = "Aluminium triflate-catalysed regioselective cycloisomerisation of non-activated unsaturated oximes",

abstract = "A novel cycloisomerisation of oximes bearing non-activated C-C double bonds occurs in an Al(III)-catalysed reaction. This process leads to 5-, 6- and 7-membered ring oxygen and nitrogen-containing heterocycles in good yields.",

keywords = "Aluminium trifluoromethansulfonate, Cycloisomerisation, Oxazepine, Oxazine, Oxime",

author = "Xavier Chaminade and Shunsuke Chiba and Koichi Narasaka and Elisabet Dunach",

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T1 - Aluminium triflate-catalysed regioselective cycloisomerisation of non-activated unsaturated oximes

AU - Chaminade, Xavier

AU - Chiba, Shunsuke

AU - Narasaka, Koichi

AU - Dunach, Elisabet

PY - 2008/4/7

Y1 - 2008/4/7

N2 - A novel cycloisomerisation of oximes bearing non-activated C-C double bonds occurs in an Al(III)-catalysed reaction. This process leads to 5-, 6- and 7-membered ring oxygen and nitrogen-containing heterocycles in good yields.

AB - A novel cycloisomerisation of oximes bearing non-activated C-C double bonds occurs in an Al(III)-catalysed reaction. This process leads to 5-, 6- and 7-membered ring oxygen and nitrogen-containing heterocycles in good yields.

KW - Aluminium trifluoromethansulfonate

KW - Cycloisomerisation

KW - Oxazepine

KW - Oxazine

KW - Oxime

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U2 - 10.1016/j.tetlet.2008.02.070

DO - 10.1016/j.tetlet.2008.02.070

M3 - Article

AN - SCOPUS:40849133759

SN - 0040-4039

VL - 49

SP - 2384

EP - 2387

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 15

ER -

Aluminium triflate-catalysed regioselective cycloisomerisation of non-activated unsaturated oximes

Abstract

ASJC Scopus Subject Areas

Keywords

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