An in-based 3D metal-organic framework as heterogeneous Lewis acid catalyst for multi-component Strecker reactions

Juan Chai; Ping Zhang; Jianing Xu; Hui Qi; Jing Sun; Shubo Jing; Xiaodong Chen; Yong Fan; Li Wang

doi:10.1016/j.ica.2018.04.037

An in-based 3D metal-organic framework as heterogeneous Lewis acid catalyst for multi-component Strecker reactions

Juan Chai, Ping Zhang, Jianing Xu, Hui Qi, Jing Sun, Shubo Jing, Xiaodong Chen, Yong Fan^*, Li Wang

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

A novel three-dimensional metal-organic framework (MOF) {[In₃(NIPH)₃ (HNIPH)(OH)₂]·4H₂O}_n (1) (H₂NIPH = 5-nitroisophthalic acid) with one-dimensional channels was synthesized and structurally characterized. Importantly, it demonstrates excellent catalytic activity for the Strecker reactions of two or three components under mild conditions. Moreover, the catalytic recycling of 1 as a representative example was explored. It can be easily separated and reused for no less than five runs with more than 80% conversion yield in catalytic ability.

Original language	English
Pages (from-to)	165-171
Number of pages	7
Journal	Inorganica Chimica Acta
Volume	479
DOIs	https://doi.org/10.1016/j.ica.2018.04.037
Publication status	Published - Jul 1 2018
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2018 Elsevier B.V.

ASJC Scopus Subject Areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Keywords

Catalyst
Metal-organic framework
Strecker reactions
Structure

Access to Document

10.1016/j.ica.2018.04.037

Cite this

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title = "An in-based 3D metal-organic framework as heterogeneous Lewis acid catalyst for multi-component Strecker reactions",

abstract = "A novel three-dimensional metal-organic framework (MOF) {[In3(NIPH)3 (HNIPH)(OH)2]·4H2O}n (1) (H2NIPH = 5-nitroisophthalic acid) with one-dimensional channels was synthesized and structurally characterized. Importantly, it demonstrates excellent catalytic activity for the Strecker reactions of two or three components under mild conditions. Moreover, the catalytic recycling of 1 as a representative example was explored. It can be easily separated and reused for no less than five runs with more than 80% conversion yield in catalytic ability.",

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T1 - An in-based 3D metal-organic framework as heterogeneous Lewis acid catalyst for multi-component Strecker reactions

AU - Chai, Juan

AU - Zhang, Ping

AU - Xu, Jianing

AU - Qi, Hui

AU - Sun, Jing

AU - Jing, Shubo

AU - Chen, Xiaodong

AU - Fan, Yong

AU - Wang, Li

PY - 2018/7/1

Y1 - 2018/7/1

N2 - A novel three-dimensional metal-organic framework (MOF) {[In3(NIPH)3 (HNIPH)(OH)2]·4H2O}n (1) (H2NIPH = 5-nitroisophthalic acid) with one-dimensional channels was synthesized and structurally characterized. Importantly, it demonstrates excellent catalytic activity for the Strecker reactions of two or three components under mild conditions. Moreover, the catalytic recycling of 1 as a representative example was explored. It can be easily separated and reused for no less than five runs with more than 80% conversion yield in catalytic ability.

AB - A novel three-dimensional metal-organic framework (MOF) {[In3(NIPH)3 (HNIPH)(OH)2]·4H2O}n (1) (H2NIPH = 5-nitroisophthalic acid) with one-dimensional channels was synthesized and structurally characterized. Importantly, it demonstrates excellent catalytic activity for the Strecker reactions of two or three components under mild conditions. Moreover, the catalytic recycling of 1 as a representative example was explored. It can be easily separated and reused for no less than five runs with more than 80% conversion yield in catalytic ability.

KW - Catalyst

KW - Metal-organic framework

KW - Strecker reactions

KW - Structure

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DO - 10.1016/j.ica.2018.04.037

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SP - 165

EP - 171

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

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An in-based 3D metal-organic framework as heterogeneous Lewis acid catalyst for multi-component Strecker reactions

Abstract

Bibliographical note

ASJC Scopus Subject Areas

Keywords

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