Aqueous C-H aminomethylation of phenols by iodine catalysis

Zhi Hua Zhou; Ben Wang; Yao Ding; Teck Peng Loh; Jie Sheng Tian

doi:10.1039/d2cc05746h

Aqueous C-H aminomethylation of phenols by iodine catalysis

Zhi Hua Zhou, Ben Wang, Yao Ding, Teck Peng Loh^*, Jie Sheng Tian^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

A transition-metal-free strategy regarding an iodine-sodium percarbonate catalysis to achieve the ortho-aminomethylation of phenols in aqueous media has been developed. This method can effectively broaden a wide range of phenols, tolerate sensitive functional groups, and achieve the late-stage functionalization of ten functional molecules that contain phenolic structures.

Original language	English
Pages (from-to)	223-226
Number of pages	4
Journal	Chemical Communications
Volume	59
Issue number	2
DOIs	https://doi.org/10.1039/d2cc05746h
Publication status	Published - Nov 30 2022
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2023 The Royal Society of Chemistry.

ASJC Scopus Subject Areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d2cc05746h

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abstract = "A transition-metal-free strategy regarding an iodine-sodium percarbonate catalysis to achieve the ortho-aminomethylation of phenols in aqueous media has been developed. This method can effectively broaden a wide range of phenols, tolerate sensitive functional groups, and achieve the late-stage functionalization of ten functional molecules that contain phenolic structures.",

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AU - Loh, Teck Peng

AU - Tian, Jie Sheng

PY - 2022/11/30

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AB - A transition-metal-free strategy regarding an iodine-sodium percarbonate catalysis to achieve the ortho-aminomethylation of phenols in aqueous media has been developed. This method can effectively broaden a wide range of phenols, tolerate sensitive functional groups, and achieve the late-stage functionalization of ten functional molecules that contain phenolic structures.

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Aqueous C-H aminomethylation of phenols by iodine catalysis

Abstract

Bibliographical note

ASJC Scopus Subject Areas

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