Assessment of butene-1,4-diols as starting materials for the preparation of π-Allyltricarbonyliron complexes

Roderick W. Bates; David Díez-Martín; William J. Kerr; Julian G. Knight; Steven V. Ley; Anna Sakellaridis

doi:10.1016/S0040-4020(01)90541-1

Assessment of butene-1,4-diols as starting materials for the preparation of π-Allyltricarbonyliron complexes

Roderick W. Bates^*, David Díez-Martín, William J. Kerr, Julian G. Knight, Steven V. Ley, Anna Sakellaridis

^*Corresponding author for this work

Imperial College London

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

This work assesses the use of butene-1,4-diols as starting materials for the synthesis of π-allyltricarbonyliron lactone complexes. It has been shown that substituents, and the use of Lewis acids, mainly ZnBr₂, in reactions with Fe₂(co)₉ in benzene under ultrasonic conditions or in THF, greatly influence the yield and the product distribution.

Original language	English
Pages (from-to)	4063-4082
Number of pages	20
Journal	Tetrahedron
Volume	46
Issue number	11
DOIs	https://doi.org/10.1016/S0040-4020(01)90541-1
Publication status	Published - 1990
Externally published	Yes

ASJC Scopus Subject Areas

Biochemistry
Drug Discovery
Organic Chemistry

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AU - Bates, Roderick W.

AU - Díez-Martín, David

AU - Kerr, William J.

AU - Knight, Julian G.

AU - Ley, Steven V.

AU - Sakellaridis, Anna

PY - 1990

Y1 - 1990

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AB - This work assesses the use of butene-1,4-diols as starting materials for the synthesis of π-allyltricarbonyliron lactone complexes. It has been shown that substituents, and the use of Lewis acids, mainly ZnBr2, in reactions with Fe2(co)9 in benzene under ultrasonic conditions or in THF, greatly influence the yield and the product distribution.

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U2 - 10.1016/S0040-4020(01)90541-1

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JF - Tetrahedron

IS - 11

ER -

Assessment of butene-1,4-diols as starting materials for the preparation of π-Allyltricarbonyliron complexes

Abstract

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