Asymmetric Wacker-Type Oxyallenylation and Azaallenylation of Cyclic Alkenes

Shenghan Teng; Zhiwei Jiao; Yonggui Robin Chi; Jianrong Steve Zhou

doi:10.1002/anie.201911961

Asymmetric Wacker-Type Oxyallenylation and Azaallenylation of Cyclic Alkenes

Shenghan Teng, Zhiwei Jiao, Yonggui Robin Chi, Jianrong Steve Zhou^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

Palladium-catalyzed three-component carboetherification of cyclic alkenes proceeded to give trans adducts exclusively with excellent enantioselectivity through a Wacker-type pathway. The reaction is also applicable to other oxygen nucleophiles, such as water, phenols, and carboxylic acids, as well as some electron-poor aryl amines.

Original language	English
Pages (from-to)	2246-2250
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	59
Issue number	6
DOIs	https://doi.org/10.1002/anie.201911961
Publication status	Published - Feb 3 2020
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

ASJC Scopus Subject Areas

Catalysis
General Chemistry

Keywords

allenes
asymmetric catalysis
carboetherification
palladium catalysis
Wacker reaction

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10.1002/anie.201911961

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abstract = "Palladium-catalyzed three-component carboetherification of cyclic alkenes proceeded to give trans adducts exclusively with excellent enantioselectivity through a Wacker-type pathway. The reaction is also applicable to other oxygen nucleophiles, such as water, phenols, and carboxylic acids, as well as some electron-poor aryl amines.",

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author = "Shenghan Teng and Zhiwei Jiao and Chi, {Yonggui Robin} and Zhou, {Jianrong Steve}",

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doi = "10.1002/anie.201911961",

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T1 - Asymmetric Wacker-Type Oxyallenylation and Azaallenylation of Cyclic Alkenes

AU - Teng, Shenghan

AU - Jiao, Zhiwei

AU - Chi, Yonggui Robin

AU - Zhou, Jianrong Steve

PY - 2020/2/3

Y1 - 2020/2/3

N2 - Palladium-catalyzed three-component carboetherification of cyclic alkenes proceeded to give trans adducts exclusively with excellent enantioselectivity through a Wacker-type pathway. The reaction is also applicable to other oxygen nucleophiles, such as water, phenols, and carboxylic acids, as well as some electron-poor aryl amines.

AB - Palladium-catalyzed three-component carboetherification of cyclic alkenes proceeded to give trans adducts exclusively with excellent enantioselectivity through a Wacker-type pathway. The reaction is also applicable to other oxygen nucleophiles, such as water, phenols, and carboxylic acids, as well as some electron-poor aryl amines.

KW - allenes

KW - asymmetric catalysis

KW - carboetherification

KW - palladium catalysis

KW - Wacker reaction

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 6

ER -

Asymmetric Wacker-Type Oxyallenylation and Azaallenylation of Cyclic Alkenes

Abstract

Bibliographical note

ASJC Scopus Subject Areas

Keywords

Access to Document

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