Abstract
The reaction of 1,4,2,5-diazadiborinine (1) with two equivalents of an aryl isonitrile afforded a bicyclic product containing an indole unit (2) or ketenimine moiety (3), suggesting the generation of a B,N-carbene intermediate formed via a [4+2] cycloaddition reaction in the initial step. The employment of the tolyl(phenyl isonitrile)gold complex (PhNCAuTol) as the substrate allowed the bicyclic (amino)(borata)carbene gold complexes (4, 5) to be accessed.
| Original language | English |
|---|---|
| Pages (from-to) | 13012-13014 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 55 |
| Issue number | 86 |
| DOIs | |
| Publication status | Published - 2019 |
| Externally published | Yes |
Bibliographical note
Publisher Copyright:This journal is © The Royal Society of Chemistry.
ASJC Scopus Subject Areas
- Electronic, Optical and Magnetic Materials
- Catalysis
- Ceramics and Composites
- General Chemistry
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry