Bisphenylbis[tetracarbonyl(hydrido)osmio]-germane, Ph2Ge[Os(CO)4H]2

Weng Kee Leong; Frederick W.B. Einstein; Roland K. Pomeroy

doi:10.1107/S0108270196012061

Bisphenylbis[tetracarbonyl(hydrido)osmio]-germane, Ph₂Ge[Os(CO)₄H]₂

Weng Kee Leong^*, Frederick W.B. Einstein, Roland K. Pomeroy

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The title compound, octacarbonyl-1κ⁴C,2κ ⁴C-dihydrido-1κH,2κH-bis(phenyl-3κC) germaniumdiosmium(2 Ge-Os), [Os₂(H)₂(CO)₈{Ge(C₆H ₅)₂}], is the first cluster containing a single Os-E-Os (E = Ge, Sn or Pb) chain to be structurally characterized. The molecule possesses approximate C₂ symmetry. The Os-Ge-Os metal chain is bent and the Os-Ge bonds [2.599(2) and 2.614 (2) Å] are the longest yet known.

Original language	English
Pages (from-to)	22-24
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	53
Issue number	1
DOIs	https://doi.org/10.1107/S0108270196012061
Publication status	Published - Jan 15 1997
Externally published	Yes

ASJC Scopus Subject Areas

General Biochemistry,Genetics and Molecular Biology

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title = "Bisphenylbis[tetracarbonyl(hydrido)osmio]-germane, Ph2Ge[Os(CO)4H]2",

abstract = "The title compound, octacarbonyl-1κ4C,2κ 4C-dihydrido-1κH,2κH-bis(phenyl-3κC) germaniumdiosmium(2 Ge-Os), [Os2(H)2(CO)8{Ge(C6H 5)2}], is the first cluster containing a single Os-E-Os (E = Ge, Sn or Pb) chain to be structurally characterized. The molecule possesses approximate C2 symmetry. The Os-Ge-Os metal chain is bent and the Os-Ge bonds [2.599(2) and 2.614 (2) {\AA}] are the longest yet known.",

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year = "1997",

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T1 - Bisphenylbis[tetracarbonyl(hydrido)osmio]-germane, Ph2Ge[Os(CO)4H]2

AU - Leong, Weng Kee

AU - Einstein, Frederick W.B.

AU - Pomeroy, Roland K.

PY - 1997/1/15

Y1 - 1997/1/15

N2 - The title compound, octacarbonyl-1κ4C,2κ 4C-dihydrido-1κH,2κH-bis(phenyl-3κC) germaniumdiosmium(2 Ge-Os), [Os2(H)2(CO)8{Ge(C6H 5)2}], is the first cluster containing a single Os-E-Os (E = Ge, Sn or Pb) chain to be structurally characterized. The molecule possesses approximate C2 symmetry. The Os-Ge-Os metal chain is bent and the Os-Ge bonds [2.599(2) and 2.614 (2) Å] are the longest yet known.

AB - The title compound, octacarbonyl-1κ4C,2κ 4C-dihydrido-1κH,2κH-bis(phenyl-3κC) germaniumdiosmium(2 Ge-Os), [Os2(H)2(CO)8{Ge(C6H 5)2}], is the first cluster containing a single Os-E-Os (E = Ge, Sn or Pb) chain to be structurally characterized. The molecule possesses approximate C2 symmetry. The Os-Ge-Os metal chain is bent and the Os-Ge bonds [2.599(2) and 2.614 (2) Å] are the longest yet known.

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Bisphenylbis[tetracarbonyl(hydrido)osmio]-germane, Ph₂Ge[Os(CO)₄H]₂

Abstract

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