Bromination of Os3(CO)11(EPh3) (E = P, Sb): Unexpected formation of a tandem donor-acceptor metal chain

Yao Liu; Weng Kee Leong; Roland K. Pomeroy

doi:10.1021/om980213l

Bromination of Os₃(CO)₁₁(EPh₃) (E = P, Sb): Unexpected formation of a tandem donor-acceptor metal chain

Yao Liu, Weng Kee Leong^*, Roland K. Pomeroy

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

Bromination of the substituted triosmium clusters Os₃(CO)₁₁(EPh₃) (E = P, Sb) yielded two trimetallic chain compounds, viz., (Br)₂Os(CO)₃Os(CO)₄Os-(CO)₄(EPh ₃) and (Br)(OC)₄OsOs(CO)₄Os(CO)₃(Br)(EPh₃) The former contains two donor-acceptor metal-metal bonds in tandem.

Original language	English
Pages (from-to)	3387-3389
Number of pages	3
Journal	Organometallics
Volume	17
Issue number	15
DOIs	https://doi.org/10.1021/om980213l
Publication status	Published - Jul 20 1998
Externally published	Yes

ASJC Scopus Subject Areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Bromination of Os3(CO)11(EPh3) (E = P, Sb): Unexpected formation of a tandem donor-acceptor metal chain",

abstract = "Bromination of the substituted triosmium clusters Os3(CO)11(EPh3) (E = P, Sb) yielded two trimetallic chain compounds, viz., (Br)2Os(CO)3Os(CO)4Os-(CO)4(EPh 3) and (Br)(OC)4OsOs(CO)4Os(CO)3(Br)(EPh3) The former contains two donor-acceptor metal-metal bonds in tandem.",

author = "Yao Liu and Leong, {Weng Kee} and Pomeroy, {Roland K.}",

year = "1998",

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doi = "10.1021/om980213l",

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journal = "Organometallics",

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T1 - Bromination of Os3(CO)11(EPh3) (E = P, Sb)

T2 - Unexpected formation of a tandem donor-acceptor metal chain

AU - Liu, Yao

AU - Leong, Weng Kee

AU - Pomeroy, Roland K.

PY - 1998/7/20

Y1 - 1998/7/20

N2 - Bromination of the substituted triosmium clusters Os3(CO)11(EPh3) (E = P, Sb) yielded two trimetallic chain compounds, viz., (Br)2Os(CO)3Os(CO)4Os-(CO)4(EPh 3) and (Br)(OC)4OsOs(CO)4Os(CO)3(Br)(EPh3) The former contains two donor-acceptor metal-metal bonds in tandem.

AB - Bromination of the substituted triosmium clusters Os3(CO)11(EPh3) (E = P, Sb) yielded two trimetallic chain compounds, viz., (Br)2Os(CO)3Os(CO)4Os-(CO)4(EPh 3) and (Br)(OC)4OsOs(CO)4Os(CO)3(Br)(EPh3) The former contains two donor-acceptor metal-metal bonds in tandem.

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IS - 15

ER -

Bromination of Os₃(CO)₁₁(EPh₃) (E = P, Sb): Unexpected formation of a tandem donor-acceptor metal chain

Abstract

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