C-C reductive coupling mediated by attack at a spectator ligand

Yongjia Li; Pek Ke Chan; Weng Kee Leong

doi:10.1016/j.jorganchem.2016.03.004

C-C reductive coupling mediated by attack at a spectator ligand

Yongjia Li, Pek Ke Chan, Weng Kee Leong^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The alkynyl ligands in the iridium(III) complex [Cp∗Ir(CO)(C≡CPh)₂] undergo reductive coupling to form the diyne complex [Cp∗Ir(CO)(PhC≡CC≡CPh)]. This process is assisted by nucleophilic attack at the carbonyl ligand by the solvent.

Original language	English
Pages (from-to)	40-45
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	810
DOIs	https://doi.org/10.1016/j.jorganchem.2016.03.004
Publication status	Published - May 15 2016
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2016 Elsevier B.V. All rights reserved.

ASJC Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Keywords

bis(alkynyl)
Diyne
Iridium
Reductive coupling
Spectator ligand

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10.1016/j.jorganchem.2016.03.004

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title = "C-C reductive coupling mediated by attack at a spectator ligand",

abstract = "The alkynyl ligands in the iridium(III) complex [Cp∗Ir(CO)(C≡CPh)2] undergo reductive coupling to form the diyne complex [Cp∗Ir(CO)(PhC≡CC≡CPh)]. This process is assisted by nucleophilic attack at the carbonyl ligand by the solvent.",

keywords = "bis(alkynyl), Diyne, Iridium, Reductive coupling, Spectator ligand",

author = "Yongjia Li and Chan, {Pek Ke} and Leong, {Weng Kee}",

year = "2016",

month = may,

day = "15",

doi = "10.1016/j.jorganchem.2016.03.004",

language = "English",

volume = "810",

pages = "40--45",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

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TY - JOUR

T1 - C-C reductive coupling mediated by attack at a spectator ligand

AU - Li, Yongjia

AU - Chan, Pek Ke

AU - Leong, Weng Kee

PY - 2016/5/15

Y1 - 2016/5/15

N2 - The alkynyl ligands in the iridium(III) complex [Cp∗Ir(CO)(C≡CPh)2] undergo reductive coupling to form the diyne complex [Cp∗Ir(CO)(PhC≡CC≡CPh)]. This process is assisted by nucleophilic attack at the carbonyl ligand by the solvent.

AB - The alkynyl ligands in the iridium(III) complex [Cp∗Ir(CO)(C≡CPh)2] undergo reductive coupling to form the diyne complex [Cp∗Ir(CO)(PhC≡CC≡CPh)]. This process is assisted by nucleophilic attack at the carbonyl ligand by the solvent.

KW - bis(alkynyl)

KW - Diyne

KW - Iridium

KW - Reductive coupling

KW - Spectator ligand

UR - http://www.scopus.com/inward/record.url?scp=84961197966&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84961197966&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2016.03.004

DO - 10.1016/j.jorganchem.2016.03.004

M3 - Article

AN - SCOPUS:84961197966

SN - 0022-328X

VL - 810

SP - 40

EP - 45

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

C-C reductive coupling mediated by attack at a spectator ligand

Abstract

Bibliographical note

ASJC Scopus Subject Areas

Keywords

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