Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex

Yong Chua Teo; Kui Thong Tan; Teck Peng Loh

doi:10.1039/b412736f

Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex

Yong Chua Teo^*, Kui Thong Tan, Teck Peng Loh

^*Corresponding author for this work

National University of Singapore

Research output: Contribution to journal › Article › peer-review

73 Citations (Scopus)

Abstract

A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributyl stannanes to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in good yields and high enantioselectivities (90-96% ee).

Original language	English
Pages (from-to)	1318-1320
Number of pages	3
Journal	Chemical Communications
Issue number	10
DOIs	https://doi.org/10.1039/b412736f
Publication status	Published - Mar 14 2005
Externally published	Yes

ASJC Scopus Subject Areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b412736f

Cite this

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title = "Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex",

abstract = "A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributyl stannanes to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in good yields and high enantioselectivities (90-96\% ee).",

author = "Teo, \{Yong Chua\} and Tan, \{Kui Thong\} and Loh, \{Teck Peng\}",

year = "2005",

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doi = "10.1039/b412736f",

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AU - Tan, Kui Thong

AU - Loh, Teck Peng

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Y1 - 2005/3/14

N2 - A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributyl stannanes to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in good yields and high enantioselectivities (90-96% ee).

AB - A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributyl stannanes to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in good yields and high enantioselectivities (90-96% ee).

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DO - 10.1039/b412736f

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex

Abstract

ASJC Scopus Subject Areas

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