Catalytic enantioselective allylation of aldehydes via a chiral indium(III) complex in ionic liquids

Yong Chua Teo; Ee Ling Goh; Teck Peng Loh

doi:10.1016/j.tetlet.2005.05.014

Catalytic enantioselective allylation of aldehydes via a chiral indium(III) complex in ionic liquids

Yong Chua Teo, Ee Ling Goh, Teck Peng Loh^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

The ionic liquid [hmim][PF₆] has been demonstrated as an efficient and environmentally-friendly reaction medium for the enantioselective allylation of aldehydes via a chiral indium(III) complex. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in moderate to good yields and enantioselectivities (upto 92% ee).

Original language	English
Pages (from-to)	4573-4575
Number of pages	3
Journal	Tetrahedron Letters
Volume	46
Issue number	27
DOIs	https://doi.org/10.1016/j.tetlet.2005.05.014
Publication status	Published - Jul 4 2005
Externally published	Yes

ASJC Scopus Subject Areas

Biochemistry
Drug Discovery
Organic Chemistry

Keywords

[hmim][PF]
Chiral indium complex
Enantioselective allylation
Ionic liquid

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10.1016/j.tetlet.2005.05.014

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title = "Catalytic enantioselective allylation of aldehydes via a chiral indium(III) complex in ionic liquids",

abstract = "The ionic liquid [hmim][PF6] has been demonstrated as an efficient and environmentally-friendly reaction medium for the enantioselective allylation of aldehydes via a chiral indium(III) complex. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in moderate to good yields and enantioselectivities (upto 92\% ee).",

keywords = "[hmim][PF], Chiral indium complex, Enantioselective allylation, Ionic liquid",

author = "Teo, \{Yong Chua\} and Goh, \{Ee Ling\} and Loh, \{Teck Peng\}",

year = "2005",

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doi = "10.1016/j.tetlet.2005.05.014",

language = "English",

volume = "46",

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journal = "Tetrahedron Letters",

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T1 - Catalytic enantioselective allylation of aldehydes via a chiral indium(III) complex in ionic liquids

AU - Teo, Yong Chua

AU - Goh, Ee Ling

AU - Loh, Teck Peng

PY - 2005/7/4

Y1 - 2005/7/4

N2 - The ionic liquid [hmim][PF6] has been demonstrated as an efficient and environmentally-friendly reaction medium for the enantioselective allylation of aldehydes via a chiral indium(III) complex. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in moderate to good yields and enantioselectivities (upto 92% ee).

AB - The ionic liquid [hmim][PF6] has been demonstrated as an efficient and environmentally-friendly reaction medium for the enantioselective allylation of aldehydes via a chiral indium(III) complex. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in moderate to good yields and enantioselectivities (upto 92% ee).

KW - [hmim][PF]

KW - Chiral indium complex

KW - Enantioselective allylation

KW - Ionic liquid

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DO - 10.1016/j.tetlet.2005.05.014

M3 - Article

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SN - 0040-4039

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EP - 4575

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 27

ER -

Catalytic enantioselective allylation of aldehydes via a chiral indium(III) complex in ionic liquids

Abstract

ASJC Scopus Subject Areas

Keywords

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