Abstract
High efficiency CZTS-based thin film solar cells are achieved by cation substitution and sol-gel method. Two approaches are presented here: 1) the substitution of Zn with Cd and 2) the substitution of Cu with Ag. For Cd-doped CZTS (i.e. CZCTS) the efficiency of CZCTS thin film solar cell can be improved from 9.24% to 10.66% by careful modification of alloys composition and interfaces between TCO/CdS/CZTS. For Ag-doped CZTS thin film solar cells, the improvement in power conversion efficiency can be correlated with the Voc and crystallinity improvements. Thus the limitations in CZTS system, such as Voc deficit, secondary phases, crystallinity and antisite defects, can be alleviated to some degree by using cation substitution.
Original language | English |
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Title of host publication | 2016 IEEE 43rd Photovoltaic Specialists Conference, PVSC 2016 |
Publisher | Institute of Electrical and Electronics Engineers Inc. |
Pages | 534-538 |
Number of pages | 5 |
ISBN (Electronic) | 9781509027248 |
DOIs | |
Publication status | Published - Nov 18 2016 |
Externally published | Yes |
Event | 43rd IEEE Photovoltaic Specialists Conference, PVSC 2016 - Portland, United States Duration: Jun 5 2016 → Jun 10 2016 |
Publication series
Name | Conference Record of the IEEE Photovoltaic Specialists Conference |
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Volume | 2016-November |
ISSN (Print) | 0160-8371 |
Conference
Conference | 43rd IEEE Photovoltaic Specialists Conference, PVSC 2016 |
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Country/Territory | United States |
City | Portland |
Period | 6/5/16 → 6/10/16 |
Bibliographical note
Publisher Copyright:© 2016 IEEE.
ASJC Scopus Subject Areas
- Control and Systems Engineering
- Industrial and Manufacturing Engineering
- Electrical and Electronic Engineering