Cation substitution of CZTS solar cell with > 10% efficiency

Zhenghua Su, W. Li, Guchhait Asim, Tay Ying Fan, Lydia Helena Wong

Research output: Chapter in Book/Report/Conference proceedingConference contribution

24 Citations (Scopus)

Abstract

High efficiency CZTS-based thin film solar cells are achieved by cation substitution and sol-gel method. Two approaches are presented here: 1) the substitution of Zn with Cd and 2) the substitution of Cu with Ag. For Cd-doped CZTS (i.e. CZCTS) the efficiency of CZCTS thin film solar cell can be improved from 9.24% to 10.66% by careful modification of alloys composition and interfaces between TCO/CdS/CZTS. For Ag-doped CZTS thin film solar cells, the improvement in power conversion efficiency can be correlated with the Voc and crystallinity improvements. Thus the limitations in CZTS system, such as Voc deficit, secondary phases, crystallinity and antisite defects, can be alleviated to some degree by using cation substitution.

Original languageEnglish
Title of host publication2016 IEEE 43rd Photovoltaic Specialists Conference, PVSC 2016
PublisherInstitute of Electrical and Electronics Engineers Inc.
Pages534-538
Number of pages5
ISBN (Electronic)9781509027248
DOIs
Publication statusPublished - Nov 18 2016
Externally publishedYes
Event43rd IEEE Photovoltaic Specialists Conference, PVSC 2016 - Portland, United States
Duration: Jun 5 2016Jun 10 2016

Publication series

NameConference Record of the IEEE Photovoltaic Specialists Conference
Volume2016-November
ISSN (Print)0160-8371

Conference

Conference43rd IEEE Photovoltaic Specialists Conference, PVSC 2016
Country/TerritoryUnited States
CityPortland
Period6/5/166/10/16

Bibliographical note

Publisher Copyright:
© 2016 IEEE.

ASJC Scopus Subject Areas

  • Control and Systems Engineering
  • Industrial and Manufacturing Engineering
  • Electrical and Electronic Engineering

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