Co-assembly of Zn(SPh) 2 and organic linkers into helical and zig-zag polymer chains

Yi Liu; Ling Min Yu; Say Chye Joachim Loo; Richard G. Blair; Qichun Zhang

doi:10.1016/j.jssc.2012.03.044

Co-assembly of Zn(SPh) ₂ and organic linkers into helical and zig-zag polymer chains

Yi Liu, Ling Min Yu, Say Chye Joachim Loo, Richard G. Blair, Qichun Zhang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Two novel one-dimensional coordination polymers, single helicate [Zn(SPh) ₂(TPyTA)(EG)] _n (EG=ethylene glycol) (1) and zig-zag structure [Zn(SPh) ₂(BPyVB)] _n (2), were synthesized under solvothermal conditions at 150 °C or room temperature by the co-assembly of Zn(SPh) ₂ and organic linkers such as 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPyTA) and 1,3-bis(trans-4-pyridylvinyl) benzene (BPyVB). X-ray crystallography study reveals that both polymers 1 and 2 crystallize in space group P2 ₁/c of the monoclinic system. The solid-state UV-vis absorption spectra show that 1 and 2 have maxium absorption onsets at 400 nm and 420 nm, respectively. TGA analysis indicates that 1 and 2 are stable up to 110 °C and 210 °C.

Original language	English
Pages (from-to)	283-286
Number of pages	4
Journal	Journal of Solid State Chemistry
Volume	191
DOIs	https://doi.org/10.1016/j.jssc.2012.03.044
Publication status	Published - Jul 2012
Externally published	Yes

ASJC Scopus Subject Areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Keywords

Coordination polymers
Organic linkers
Single helicate
Zig-zag structure

Access to Document

10.1016/j.jssc.2012.03.044

Cite this

@article{607eac24aee54edc946780760d98a079,

title = "Co-assembly of Zn(SPh) 2 and organic linkers into helical and zig-zag polymer chains",

abstract = "Two novel one-dimensional coordination polymers, single helicate [Zn(SPh) 2(TPyTA)(EG)] n (EG=ethylene glycol) (1) and zig-zag structure [Zn(SPh) 2(BPyVB)] n (2), were synthesized under solvothermal conditions at 150 °C or room temperature by the co-assembly of Zn(SPh) 2 and organic linkers such as 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPyTA) and 1,3-bis(trans-4-pyridylvinyl) benzene (BPyVB). X-ray crystallography study reveals that both polymers 1 and 2 crystallize in space group P2 1/c of the monoclinic system. The solid-state UV-vis absorption spectra show that 1 and 2 have maxium absorption onsets at 400 nm and 420 nm, respectively. TGA analysis indicates that 1 and 2 are stable up to 110 °C and 210 °C.",

keywords = "Coordination polymers, Organic linkers, Single helicate, Zig-zag structure",

author = "Yi Liu and Yu, {Ling Min} and Loo, {Say Chye Joachim} and Blair, {Richard G.} and Qichun Zhang",

year = "2012",

month = jul,

doi = "10.1016/j.jssc.2012.03.044",

language = "English",

volume = "191",

pages = "283--286",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

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TY - JOUR

T1 - Co-assembly of Zn(SPh) 2 and organic linkers into helical and zig-zag polymer chains

AU - Liu, Yi

AU - Yu, Ling Min

AU - Loo, Say Chye Joachim

AU - Blair, Richard G.

AU - Zhang, Qichun

PY - 2012/7

Y1 - 2012/7

N2 - Two novel one-dimensional coordination polymers, single helicate [Zn(SPh) 2(TPyTA)(EG)] n (EG=ethylene glycol) (1) and zig-zag structure [Zn(SPh) 2(BPyVB)] n (2), were synthesized under solvothermal conditions at 150 °C or room temperature by the co-assembly of Zn(SPh) 2 and organic linkers such as 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPyTA) and 1,3-bis(trans-4-pyridylvinyl) benzene (BPyVB). X-ray crystallography study reveals that both polymers 1 and 2 crystallize in space group P2 1/c of the monoclinic system. The solid-state UV-vis absorption spectra show that 1 and 2 have maxium absorption onsets at 400 nm and 420 nm, respectively. TGA analysis indicates that 1 and 2 are stable up to 110 °C and 210 °C.

AB - Two novel one-dimensional coordination polymers, single helicate [Zn(SPh) 2(TPyTA)(EG)] n (EG=ethylene glycol) (1) and zig-zag structure [Zn(SPh) 2(BPyVB)] n (2), were synthesized under solvothermal conditions at 150 °C or room temperature by the co-assembly of Zn(SPh) 2 and organic linkers such as 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPyTA) and 1,3-bis(trans-4-pyridylvinyl) benzene (BPyVB). X-ray crystallography study reveals that both polymers 1 and 2 crystallize in space group P2 1/c of the monoclinic system. The solid-state UV-vis absorption spectra show that 1 and 2 have maxium absorption onsets at 400 nm and 420 nm, respectively. TGA analysis indicates that 1 and 2 are stable up to 110 °C and 210 °C.

KW - Coordination polymers

KW - Organic linkers

KW - Single helicate

KW - Zig-zag structure

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