Complexation of asymmetric diborenes with magnesium bromide

Wei Lu, Rei Kinjo*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

14 Citations (Scopus)

Abstract

The synthesis of neutral Mg complexes of asymmetric diborenes is reported. X-ray diffraction analysis reveals that the Mg center is unsymmetrically coordinated to the B2 units of diborenes. Theoretical calculations manifest the donation of electrons from the π-type orbitals of diborenes to an empty orbital of Mg.

Original languageEnglish
Pages (from-to)8842-8844
Number of pages3
JournalChemical Communications
Volume54
Issue number64
DOIs
Publication statusPublished - 2018
Externally publishedYes

Bibliographical note

Publisher Copyright:
© The Royal Society of Chemistry.

ASJC Scopus Subject Areas

  • Electronic, Optical and Magnetic Materials
  • Catalysis
  • Ceramics and Composites
  • General Chemistry
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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