Coordination-insertion copolymerization of allyl monomers with ethylene

Shingo Ito, Masafumi Kanazawa, Kagehiro Munakata, Jun Ichi Kuroda, Yoshikuni Okumura, Kyoko Nozaki*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

120 Citations (Scopus)

Abstract

Coordination-insertion copolymerization of allyl monomers with ethylene was developed by using a palladium/phosphine-sulfonate catalyst. A variety of allyl monomers, including allyl acetate, allyl alcohol, protected allylamines, and allyl halides, were copolymerized with ethylene to form highly linear copolymers that possess in-chain -CH2CH(CH2FG)- units.

Original languageEnglish
Pages (from-to)1232-1235
Number of pages4
JournalJournal of the American Chemical Society
Volume133
Issue number5
DOIs
Publication statusPublished - Feb 9 2011
Externally publishedYes

ASJC Scopus Subject Areas

  • Catalysis
  • General Chemistry
  • Biochemistry
  • Colloid and Surface Chemistry

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