Copper-catalyzed regiodivergent 1,4-and 1,6-conjugate silyl addition to diendioates: Access to functionalized allylsilanes

Tanveer Ahmad; Qi Li; Sheng Qi Qiu; Jian Lin Xu; Yun He Xu; Teck Peng Loh

doi:10.1039/c9ob01086f

Copper-catalyzed regiodivergent 1,4-and 1,6-conjugate silyl addition to diendioates: Access to functionalized allylsilanes

Tanveer Ahmad, Qi Li, Sheng Qi Qiu, Jian Lin Xu, Yun He Xu^*, Teck Peng Loh

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

A copper-catalyzed regioselective 1,4-and 1,6-conjugate addition of a silyl reagent to diendioates was established. Various 1,4-and 1,6-protosilylation products were obtained in good yields and with high regioselectivity via tuning the ligands used in the reactions. This protocol has provided a simple and efficient method for the synthesis of multisubstituted functionalized allylsilanes.

Original language	English
Pages (from-to)	6122-6126
Number of pages	5
Journal	Organic and Biomolecular Chemistry
Volume	17
Issue number	25
DOIs	https://doi.org/10.1039/c9ob01086f
Publication status	Published - 2019
Externally published	Yes

Bibliographical note

Publisher Copyright:
This journal is © The Royal Society of Chemistry.

ASJC Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1039/c9ob01086f

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abstract = "A copper-catalyzed regioselective 1,4-and 1,6-conjugate addition of a silyl reagent to diendioates was established. Various 1,4-and 1,6-protosilylation products were obtained in good yields and with high regioselectivity via tuning the ligands used in the reactions. This protocol has provided a simple and efficient method for the synthesis of multisubstituted functionalized allylsilanes.",

author = "Tanveer Ahmad and Qi Li and Qiu, \{Sheng Qi\} and Xu, \{Jian Lin\} and Xu, \{Yun He\} and Loh, \{Teck Peng\}",

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doi = "10.1039/c9ob01086f",

language = "English",

volume = "17",

pages = "6122--6126",

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T1 - Copper-catalyzed regiodivergent 1,4-and 1,6-conjugate silyl addition to diendioates

T2 - Access to functionalized allylsilanes

AU - Ahmad, Tanveer

AU - Li, Qi

AU - Qiu, Sheng Qi

AU - Xu, Jian Lin

AU - Xu, Yun He

AU - Loh, Teck Peng

PY - 2019

Y1 - 2019

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AB - A copper-catalyzed regioselective 1,4-and 1,6-conjugate addition of a silyl reagent to diendioates was established. Various 1,4-and 1,6-protosilylation products were obtained in good yields and with high regioselectivity via tuning the ligands used in the reactions. This protocol has provided a simple and efficient method for the synthesis of multisubstituted functionalized allylsilanes.

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EP - 6126

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 25

ER -

Copper-catalyzed regiodivergent 1,4-and 1,6-conjugate silyl addition to diendioates: Access to functionalized allylsilanes

Abstract

Bibliographical note

ASJC Scopus Subject Areas

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