[Cp*IrCl2]2-assisted C=C bond cleavage with water: An experimental and computational study

Venugopal Shanmugham Sridevi; Yip Fan Wai; Kee Leong Weng

doi:10.1021/om0610445

[Cp*IrCl₂]₂-assisted C=C bond cleavage with water: An experimental and computational study

Venugopal Shanmugham Sridevi, Yip Fan Wai, Kee Leong Weng^*

^*Corresponding author for this work

National University of Singapore

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Reaction of the dimeric species [Cp*IrCl₂]₂ with a number of organic substrates carrying a terminal alkyne functionality (RCCH) in the presence of water leads to C=C bond cleavage to form Cp*IrCl-(CH₂R)(CO). The reaction pathway has been studied both experimentally and computationally.

Original language	English
Pages (from-to)	1173-1177
Number of pages	5
Journal	Organometallics
Volume	26
Issue number	5
DOIs	https://doi.org/10.1021/om0610445
Publication status	Published - Feb 26 2007
Externally published	Yes

ASJC Scopus Subject Areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om0610445

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abstract = "Reaction of the dimeric species [Cp*IrCl2]2 with a number of organic substrates carrying a terminal alkyne functionality (RCCH) in the presence of water leads to C=C bond cleavage to form Cp*IrCl-(CH2R)(CO). The reaction pathway has been studied both experimentally and computationally.",

author = "Sridevi, {Venugopal Shanmugham} and Wai, {Yip Fan} and Weng, {Kee Leong}",

year = "2007",

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AU - Sridevi, Venugopal Shanmugham

AU - Wai, Yip Fan

AU - Weng, Kee Leong

PY - 2007/2/26

Y1 - 2007/2/26

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AB - Reaction of the dimeric species [Cp*IrCl2]2 with a number of organic substrates carrying a terminal alkyne functionality (RCCH) in the presence of water leads to C=C bond cleavage to form Cp*IrCl-(CH2R)(CO). The reaction pathway has been studied both experimentally and computationally.

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[Cp*IrCl₂]₂-assisted C=C bond cleavage with water: An experimental and computational study

Abstract

ASJC Scopus Subject Areas

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