[Cp*IrCl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines

Elumalai Kumaran; Wai Yip Fan; Weng Kee Leong

doi:10.1021/ol5000692

[Cp*IrCl₂]₂ catalyzed formation of 2,2′-biindoles from 2-ethynylanilines

Elumalai Kumaran, Wai Yip Fan, Weng Kee Leong^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

[Cp*IrCl₂]₂ catalyzes the cyclization of 2-ethynylanilines to 2,2′-biindoles via intramolecular hydroamination. A reaction pathway has been proposed on the basis of deuterium labeling experiments and computational studies.

Original language	English
Pages (from-to)	1342-1345
Number of pages	4
Journal	Organic Letters
Volume	16
Issue number	5
DOIs	https://doi.org/10.1021/ol5000692
Publication status	Published - Mar 7 2014
Externally published	Yes

ASJC Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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title = "[Cp*IrCl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines",

abstract = "[Cp*IrCl2]2 catalyzes the cyclization of 2-ethynylanilines to 2,2′-biindoles via intramolecular hydroamination. A reaction pathway has been proposed on the basis of deuterium labeling experiments and computational studies.",

author = "Elumalai Kumaran and Fan, {Wai Yip} and Leong, {Weng Kee}",

year = "2014",

month = mar,

day = "7",

doi = "10.1021/ol5000692",

language = "English",

volume = "16",

pages = "1342--1345",

journal = "Organic Letters",

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T1 - [Cp*IrCl2]2 catalyzed formation of 2,2′-biindoles from 2-ethynylanilines

AU - Kumaran, Elumalai

AU - Fan, Wai Yip

AU - Leong, Weng Kee

PY - 2014/3/7

Y1 - 2014/3/7

N2 - [Cp*IrCl2]2 catalyzes the cyclization of 2-ethynylanilines to 2,2′-biindoles via intramolecular hydroamination. A reaction pathway has been proposed on the basis of deuterium labeling experiments and computational studies.

AB - [Cp*IrCl2]2 catalyzes the cyclization of 2-ethynylanilines to 2,2′-biindoles via intramolecular hydroamination. A reaction pathway has been proposed on the basis of deuterium labeling experiments and computational studies.

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U2 - 10.1021/ol5000692

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JO - Organic Letters

JF - Organic Letters

IS - 5

ER -

[Cp*IrCl₂]₂ catalyzed formation of 2,2′-biindoles from 2-ethynylanilines

Abstract

ASJC Scopus Subject Areas

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