Crystalline boron-linked tetraaminoethylene radical cations

Yuanting Su; Yongxin Li; Rakesh Ganguly; Rei Kinjo

doi:10.1039/c7sc03528d

Crystalline boron-linked tetraaminoethylene radical cations

Yuanting Su, Yongxin Li, Rakesh Ganguly, Rei Kinjo^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Single-electron oxidation of neutral boryl-linked tetraaminoethylene derivatives 4 led to the formation of radical cations 4⁺, which have been isolated and fully characterized. X-ray diffraction analysis, EPR spectroscopy, and computational studies revealed that the unpaired electron is delocalized over the B₂N₄C₂ skeleton and the spin density mainly resides on the carbon and boron atoms.

Original language	English
Pages (from-to)	7419-7423
Number of pages	5
Journal	Chemical Science
Volume	8
Issue number	11
DOIs	https://doi.org/10.1039/c7sc03528d
Publication status	Published - 2017
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2017 The Royal Society of Chemistry.

ASJC Scopus Subject Areas

General Chemistry

Access to Document

10.1039/c7sc03528d

Cite this

@article{5905e8ed59d3447ea0b6d3e9b920ca7f,

title = "Crystalline boron-linked tetraaminoethylene radical cations",

abstract = "Single-electron oxidation of neutral boryl-linked tetraaminoethylene derivatives 4 led to the formation of radical cations 4+, which have been isolated and fully characterized. X-ray diffraction analysis, EPR spectroscopy, and computational studies revealed that the unpaired electron is delocalized over the B2N4C2 skeleton and the spin density mainly resides on the carbon and boron atoms.",

author = "Yuanting Su and Yongxin Li and Rakesh Ganguly and Rei Kinjo",

note = "Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c7sc03528d",

language = "English",

volume = "8",

pages = "7419--7423",

journal = "Chemical Science",

issn = "2041-6520",

publisher = "Royal Society of Chemistry",

number = "11",

}

TY - JOUR

T1 - Crystalline boron-linked tetraaminoethylene radical cations

AU - Su, Yuanting

AU - Li, Yongxin

AU - Ganguly, Rakesh

AU - Kinjo, Rei

PY - 2017

Y1 - 2017

N2 - Single-electron oxidation of neutral boryl-linked tetraaminoethylene derivatives 4 led to the formation of radical cations 4+, which have been isolated and fully characterized. X-ray diffraction analysis, EPR spectroscopy, and computational studies revealed that the unpaired electron is delocalized over the B2N4C2 skeleton and the spin density mainly resides on the carbon and boron atoms.

AB - Single-electron oxidation of neutral boryl-linked tetraaminoethylene derivatives 4 led to the formation of radical cations 4+, which have been isolated and fully characterized. X-ray diffraction analysis, EPR spectroscopy, and computational studies revealed that the unpaired electron is delocalized over the B2N4C2 skeleton and the spin density mainly resides on the carbon and boron atoms.

UR - http://www.scopus.com/inward/record.url?scp=85031996435&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85031996435&partnerID=8YFLogxK

U2 - 10.1039/c7sc03528d

DO - 10.1039/c7sc03528d

M3 - Article

AN - SCOPUS:85031996435

SN - 2041-6520

VL - 8

SP - 7419

EP - 7423

JO - Chemical Science

JF - Chemical Science

IS - 11

ER -

Crystalline boron-linked tetraaminoethylene radical cations

Abstract

Bibliographical note

ASJC Scopus Subject Areas

Access to Document

Other files and links

Fingerprint

Cite this