Crystallization of carbon nanotube and nanofiber polypropylene composites

J. Sandler, G. Broza, M. Nolte, K. Schulte, Y. M. Lam, M. S.P. Shaffer*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

107 Citations (Scopus)

Abstract

A variety of semicrystalline isotactic polypropylene composites containing carbon nanotubes and nanofibers were produced by melt and solution techniques. The effect of the nanofillers on the crystallization process was investigated by transmission electron microscopy, scanning electron microscopy, and differential scanning calorimetry. Under the processing conditions applied in this study, the surfaces of the carbon nanomaterials act as nucleation sites in bulk samples and highly oriented composite films. This conclusion is confirmed by the calculation of Avrami exponents and, in particular, by direct microscopy evidence.

Original languageEnglish
Pages (from-to)479-488
Number of pages10
JournalJournal of Macromolecular Science - Physics
Volume42 B
Issue number3-4 SPEC.
DOIs
Publication statusPublished - 2003
Externally publishedYes

ASJC Scopus Subject Areas

  • General Chemistry
  • Condensed Matter Physics
  • Polymers and Plastics
  • Materials Chemistry

Keywords

  • Carbon nanofibers
  • Carbon nanotubes
  • Crystallization
  • Nanocomposites
  • Nucleation
  • Polypropylene

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