Cu(II)-mediated aminooxygenation of alkenylimines and alkenylamidines with TEMPO

Stephen Sanjaya; Sze Hui Chua; Shunsuke Chiba

doi:10.1055/s-0031-1291157

Cu(II)-mediated aminooxygenation of alkenylimines and alkenylamidines with TEMPO

Stephen Sanjaya, Sze Hui Chua, Shunsuke Chiba^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

A method for the synthesis of oxymethyl dihydropyrroles (pyrrolines) and dihydroimidazoles has been developed via Cu(II)-mediated intramolecular aminooxygenation of alkenylimines and alkenylamidines, respectively, with 2,2,6,6-tetramethyl-1-piperidinyloxy radical (TEMPO).

Original language	English
Pages (from-to)	1657-1661
Number of pages	5
Journal	Synlett
Volume	23
Issue number	11
DOIs	https://doi.org/10.1055/s-0031-1291157
Publication status	Published - 2012
Externally published	Yes

ASJC Scopus Subject Areas

Organic Chemistry

Keywords

copper
dihydroimidazoles
dihydropyrroles (pyrrolines)
TEMPO

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10.1055/s-0031-1291157

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title = "Cu(II)-mediated aminooxygenation of alkenylimines and alkenylamidines with TEMPO",

abstract = "A method for the synthesis of oxymethyl dihydropyrroles (pyrrolines) and dihydroimidazoles has been developed via Cu(II)-mediated intramolecular aminooxygenation of alkenylimines and alkenylamidines, respectively, with 2,2,6,6-tetramethyl-1-piperidinyloxy radical (TEMPO).",

keywords = "copper, dihydroimidazoles, dihydropyrroles (pyrrolines), TEMPO",

author = "Stephen Sanjaya and Chua, {Sze Hui} and Shunsuke Chiba",

year = "2012",

doi = "10.1055/s-0031-1291157",

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T1 - Cu(II)-mediated aminooxygenation of alkenylimines and alkenylamidines with TEMPO

AU - Sanjaya, Stephen

AU - Chua, Sze Hui

AU - Chiba, Shunsuke

PY - 2012

Y1 - 2012

N2 - A method for the synthesis of oxymethyl dihydropyrroles (pyrrolines) and dihydroimidazoles has been developed via Cu(II)-mediated intramolecular aminooxygenation of alkenylimines and alkenylamidines, respectively, with 2,2,6,6-tetramethyl-1-piperidinyloxy radical (TEMPO).

AB - A method for the synthesis of oxymethyl dihydropyrroles (pyrrolines) and dihydroimidazoles has been developed via Cu(II)-mediated intramolecular aminooxygenation of alkenylimines and alkenylamidines, respectively, with 2,2,6,6-tetramethyl-1-piperidinyloxy radical (TEMPO).

KW - copper

KW - dihydroimidazoles

KW - dihydropyrroles (pyrrolines)

KW - TEMPO

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U2 - 10.1055/s-0031-1291157

DO - 10.1055/s-0031-1291157

M3 - Article

AN - SCOPUS:84862770259

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JO - Synlett

JF - Synlett

IS - 11

ER -

Cu(II)-mediated aminooxygenation of alkenylimines and alkenylamidines with TEMPO

Abstract

ASJC Scopus Subject Areas

Keywords

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