Cyclic thioether and acyclic thioether-thiolate complexes of pentamethylcyclopentadienyl ruthenium(II, III)

Lai Yoong Goh; Ming Ern Teo; Soo Beng Khoo; Weng Kee Leong; Jagadese J. Vittal

doi:10.1016/S0022-328X(02)01977-0

Cyclic thioether and acyclic thioether-thiolate complexes of pentamethylcyclopentadienyl ruthenium(II, III)

Lai Yoong Goh^*, Ming Ern Teo, Soo Beng Khoo, Weng Kee Leong, Jagadese J. Vittal

^*Corresponding author for this work

National University of Singapore

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

The reaction of [Cp^*RuCl₂]₂ (7) (Cp* = η⁵-C₅Me₅) with S(CH₂CH₂S^-)₂ (tpdt) and trithiacyclononane (9S3) gave the monomeric complexes Cp^*Ru(tpdt) (6) and [Cp^*Ru(9S3)](PF₆) (8) as dark purple and yellow crystals, respectively. Treatment of 6 with 7 and [(C₆Me₆)RuCl₂]₂ (2) led to the isolation of Ru-Ru bonded complexes [Cp^*Ru(tpdt)(Ru(Cl)Cp^*](PF₆) (9) and [Cp Ru(tpd-(tpd)(Ru(C₆)](PF₆) (10) as dark red and purple crystals, respectively. The complexes, 6 and 8-10 have been spectrally and structurally characterized.

Original language	English
Pages (from-to)	161-169
Number of pages	9
Journal	Journal of Organometallic Chemistry
Volume	664
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-328X(02)01977-0
Publication status	Published - Dec 16 2002
Externally published	Yes

ASJC Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "Cyclic thioether and acyclic thioether-thiolate complexes of pentamethylcyclopentadienyl ruthenium(II, III)",

abstract = "The reaction of [Cp*RuCl2]2 (7) (Cp* = η5-C5Me5) with S(CH2CH2S-)2 (tpdt) and trithiacyclononane (9S3) gave the monomeric complexes Cp*Ru(tpdt) (6) and [Cp*Ru(9S3)](PF6) (8) as dark purple and yellow crystals, respectively. Treatment of 6 with 7 and [(C6Me6)RuCl2]2 (2) led to the isolation of Ru-Ru bonded complexes [Cp*Ru(tpdt)(Ru(Cl)Cp*](PF6) (9) and [Cp Ru(tpd-(tpd)(Ru(C6)](PF6) (10) as dark red and purple crystals, respectively. The complexes, 6 and 8-10 have been spectrally and structurally characterized.",

author = "Goh, {Lai Yoong} and Teo, {Ming Ern} and Khoo, {Soo Beng} and Leong, {Weng Kee} and Vittal, {Jagadese J.}",

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T1 - Cyclic thioether and acyclic thioether-thiolate complexes of pentamethylcyclopentadienyl ruthenium(II, III)

AU - Goh, Lai Yoong

AU - Teo, Ming Ern

AU - Khoo, Soo Beng

AU - Leong, Weng Kee

AU - Vittal, Jagadese J.

PY - 2002/12/16

Y1 - 2002/12/16

N2 - The reaction of [Cp*RuCl2]2 (7) (Cp* = η5-C5Me5) with S(CH2CH2S-)2 (tpdt) and trithiacyclononane (9S3) gave the monomeric complexes Cp*Ru(tpdt) (6) and [Cp*Ru(9S3)](PF6) (8) as dark purple and yellow crystals, respectively. Treatment of 6 with 7 and [(C6Me6)RuCl2]2 (2) led to the isolation of Ru-Ru bonded complexes [Cp*Ru(tpdt)(Ru(Cl)Cp*](PF6) (9) and [Cp Ru(tpd-(tpd)(Ru(C6)](PF6) (10) as dark red and purple crystals, respectively. The complexes, 6 and 8-10 have been spectrally and structurally characterized.

AB - The reaction of [Cp*RuCl2]2 (7) (Cp* = η5-C5Me5) with S(CH2CH2S-)2 (tpdt) and trithiacyclononane (9S3) gave the monomeric complexes Cp*Ru(tpdt) (6) and [Cp*Ru(9S3)](PF6) (8) as dark purple and yellow crystals, respectively. Treatment of 6 with 7 and [(C6Me6)RuCl2]2 (2) led to the isolation of Ru-Ru bonded complexes [Cp*Ru(tpdt)(Ru(Cl)Cp*](PF6) (9) and [Cp Ru(tpd-(tpd)(Ru(C6)](PF6) (10) as dark red and purple crystals, respectively. The complexes, 6 and 8-10 have been spectrally and structurally characterized.

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JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Cyclic thioether and acyclic thioether-thiolate complexes of pentamethylcyclopentadienyl ruthenium(II, III)

Abstract

ASJC Scopus Subject Areas

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