Design and synthesis of a water-tolerant chiral indium complex: Application to one-pot three-component Mannich-type reactions in water

Jian Xiao; Teck Peng Loh

doi:10.1055/s-2007-970774

Design and synthesis of a water-tolerant chiral indium complex: Application to one-pot three-component Mannich-type reactions in water

Jian Xiao, Teck Peng Loh^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

A novel chiral indium(III) camphorsulfonate complex prepared from indium trichloride, allyltributylstannane and (1S)-(+)-10-camphorsulfonic acid has been developed as a water-tolerant Lewis acid to afford high yields (up to 99%) in one-pot three-component Mannich-type reactions in a true water environment.

Original language	English
Pages (from-to)	815-817
Number of pages	3
Journal	Synlett
Issue number	5
DOIs	https://doi.org/10.1055/s-2007-970774
Publication status	Published - Mar 16 2007
Externally published	Yes

ASJC Scopus Subject Areas

Organic Chemistry

Keywords

Allyltributylstannane
Chiral indium complex
One-pot three-component Mannich-type reaction

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10.1055/s-2007-970774

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abstract = "A novel chiral indium(III) camphorsulfonate complex prepared from indium trichloride, allyltributylstannane and (1S)-(+)-10-camphorsulfonic acid has been developed as a water-tolerant Lewis acid to afford high yields (up to 99%) in one-pot three-component Mannich-type reactions in a true water environment.",

keywords = "Allyltributylstannane, Chiral indium complex, One-pot three-component Mannich-type reaction",

author = "Jian Xiao and Loh, {Teck Peng}",

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AU - Loh, Teck Peng

PY - 2007/3/16

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AB - A novel chiral indium(III) camphorsulfonate complex prepared from indium trichloride, allyltributylstannane and (1S)-(+)-10-camphorsulfonic acid has been developed as a water-tolerant Lewis acid to afford high yields (up to 99%) in one-pot three-component Mannich-type reactions in a true water environment.

KW - Allyltributylstannane

KW - Chiral indium complex

KW - One-pot three-component Mannich-type reaction

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Design and synthesis of a water-tolerant chiral indium complex: Application to one-pot three-component Mannich-type reactions in water

Abstract

ASJC Scopus Subject Areas

Keywords

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