Development of a highly α-regioselective indium-mediated allylation reaction in water

Teck Peng Loh; Kui Thong Tan; Jian Ying Yang; Chao Li Xiang

doi:10.1016/S0040-4039(01)01883-4

Development of a highly α-regioselective indium-mediated allylation reaction in water

Teck Peng Loh^*, Kui Thong Tan, Jian Ying Yang, Chao Li Xiang

^*Corresponding author for this work

National University of Singapore

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

Linear α homoallylic alcohol adducts were obtained with high regioselectivities in moderate to good yields using allylic indium reagents in the presence of 10 M water. The exceptionally high regioselectivities observed were neither steric nor electronic in origin from the results presented in this paper.

Original language	English
Pages (from-to)	8701-8703
Number of pages	3
Journal	Tetrahedron Letters
Volume	42
Issue number	49
DOIs	https://doi.org/10.1016/S0040-4039(01)01883-4
Publication status	Published - Dec 3 2001
Externally published	Yes

ASJC Scopus Subject Areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(01)01883-4

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title = "Development of a highly α-regioselective indium-mediated allylation reaction in water",

abstract = "Linear α homoallylic alcohol adducts were obtained with high regioselectivities in moderate to good yields using allylic indium reagents in the presence of 10 M water. The exceptionally high regioselectivities observed were neither steric nor electronic in origin from the results presented in this paper.",

author = "Loh, {Teck Peng} and Tan, {Kui Thong} and Yang, {Jian Ying} and Xiang, {Chao Li}",

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T1 - Development of a highly α-regioselective indium-mediated allylation reaction in water

AU - Loh, Teck Peng

AU - Tan, Kui Thong

AU - Yang, Jian Ying

AU - Xiang, Chao Li

PY - 2001/12/3

Y1 - 2001/12/3

N2 - Linear α homoallylic alcohol adducts were obtained with high regioselectivities in moderate to good yields using allylic indium reagents in the presence of 10 M water. The exceptionally high regioselectivities observed were neither steric nor electronic in origin from the results presented in this paper.

AB - Linear α homoallylic alcohol adducts were obtained with high regioselectivities in moderate to good yields using allylic indium reagents in the presence of 10 M water. The exceptionally high regioselectivities observed were neither steric nor electronic in origin from the results presented in this paper.

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U2 - 10.1016/S0040-4039(01)01883-4

DO - 10.1016/S0040-4039(01)01883-4

M3 - Article

AN - SCOPUS:0035803050

SN - 0040-4039

VL - 42

SP - 8701

EP - 8703

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 49

ER -

Development of a highly α-regioselective indium-mediated allylation reaction in water

Abstract

ASJC Scopus Subject Areas

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