Abstract
This chapter contains sections titled: Development of a highly regioselective metal-mediated allylation reaction in aqueous media Boronic acids as aryl source for the catalysed enantioselective aryl transfer to aldehydes Jacobsen’s Salen as a chiral ligand for the chromium-catalysed addition of 3-chloro-propenyl pivalate to aldehydes: a catalytic asymmetric entry to syn-alk-1-ene-3,4-diols.
| Original language | English |
|---|---|
| Title of host publication | Catalysts for Fine Chemical Synthesis |
| Subtitle of host publication | Metal Catalysed Carbon-Carbon Bond-Forming Reactions |
| Publisher | wiley |
| Pages | 156-161 |
| Number of pages | 6 |
| Volume | 3 |
| ISBN (Electronic) | 9780470862018 |
| ISBN (Print) | 9780470861998 |
| DOIs | |
| Publication status | Published - Jan 1 2005 |
| Externally published | Yes |
Bibliographical note
Publisher Copyright:© 2004 John Wiley & Sons, Ltd.
ASJC Scopus Subject Areas
- General Chemistry
Keywords
- 3-chloro-propenyl pivalate synthesis
- Enantiopure diaryl methanols
- Homoallylic alcohols
- Indium-mediated allylation
- Metal-mediated allylation reaction
- Metal-mediated Barbier-type allylation
- Nozaki-Hiyama-Kishi (NHK) reaction
- Salen-Cr(II) catalysed system
- Trimethylsilyl chloride (TMSCl)