Diastereoselective cobalt-mediated acylation-cyclization of allenes

R. W. Bates; V. Satcharoen

doi:10.1055/s-2001-12335

Diastereoselective cobalt-mediated acylation-cyclization of allenes

R. W. Bates^*, V. Satcharoen

^*Corresponding author for this work

Chulabhorn Research Institute

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Allenes with α-oxygen and γ-sulfonamide substituents were synthesized and cyclized to pyrrolidines using an acyl cobalt reagent. The reactions proceeded with very high trans selectivity.

Original language	English
Pages (from-to)	532-534
Number of pages	3
Journal	Synlett
Issue number	4
DOIs	https://doi.org/10.1055/s-2001-12335
Publication status	Published - 2001
Externally published	Yes

ASJC Scopus Subject Areas

Organic Chemistry

Keywords

Allene
Cobalt
Cyclization
Diastereoselectivity
Pyrrolidine

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10.1055/s-2001-12335

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title = "Diastereoselective cobalt-mediated acylation-cyclization of allenes",

abstract = "Allenes with α-oxygen and γ-sulfonamide substituents were synthesized and cyclized to pyrrolidines using an acyl cobalt reagent. The reactions proceeded with very high trans selectivity.",

keywords = "Allene, Cobalt, Cyclization, Diastereoselectivity, Pyrrolidine",

author = "Bates, {R. W.} and V. Satcharoen",

year = "2001",

doi = "10.1055/s-2001-12335",

language = "English",

pages = "532--534",

journal = "Synlett",

issn = "0936-5214",

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T1 - Diastereoselective cobalt-mediated acylation-cyclization of allenes

AU - Bates, R. W.

AU - Satcharoen, V.

PY - 2001

Y1 - 2001

N2 - Allenes with α-oxygen and γ-sulfonamide substituents were synthesized and cyclized to pyrrolidines using an acyl cobalt reagent. The reactions proceeded with very high trans selectivity.

AB - Allenes with α-oxygen and γ-sulfonamide substituents were synthesized and cyclized to pyrrolidines using an acyl cobalt reagent. The reactions proceeded with very high trans selectivity.

KW - Allene

KW - Cobalt

KW - Cyclization

KW - Diastereoselectivity

KW - Pyrrolidine

UR - http://www.scopus.com/inward/record.url?scp=0035070313&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0035070313&partnerID=8YFLogxK

U2 - 10.1055/s-2001-12335

DO - 10.1055/s-2001-12335

M3 - Article

AN - SCOPUS:0035070313

SN - 0936-5214

SP - 532

EP - 534

JO - Synlett

JF - Synlett

IS - 4

ER -

Diastereoselective cobalt-mediated acylation-cyclization of allenes

Abstract

ASJC Scopus Subject Areas

Keywords

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