Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene: Electron deficiency compensation by asymmetric structural changes

Madelyn Qin Yi Tay; Balasubramanian Murugesapandian; Yunpeng Lu; Rakesh Ganguly; Kinjo Rei; Dragoslav Vidović

doi:10.1039/c4dt01210k

Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene: Electron deficiency compensation by asymmetric structural changes

Madelyn Qin Yi Tay^*, Balasubramanian Murugesapandian, Yunpeng Lu, Rakesh Ganguly, Kinjo Rei, Dragoslav Vidović

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The synthesis, characterization and X-ray analysis of dichloro- and dibromo-borenium cations stabilized by a 4-membered carbene are reported. The ligand's structural changes, atypical for similar systems, were caused by coordination to electron deficient fragments and its CN₂P ring strain.

Original language	English
Pages (from-to)	15313-15316
Number of pages	4
Journal	Dalton Transactions
Volume	43
Issue number	41
DOIs	https://doi.org/10.1039/c4dt01210k
Publication status	Published - Nov 7 2014
Externally published	Yes

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© the Partner Organisations 2014.

ASJC Scopus Subject Areas

Inorganic Chemistry

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abstract = "The synthesis, characterization and X-ray analysis of dichloro- and dibromo-borenium cations stabilized by a 4-membered carbene are reported. The ligand's structural changes, atypical for similar systems, were caused by coordination to electron deficient fragments and its CN2P ring strain.",

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T2 - Electron deficiency compensation by asymmetric structural changes

AU - Tay, Madelyn Qin Yi

AU - Murugesapandian, Balasubramanian

AU - Lu, Yunpeng

AU - Ganguly, Rakesh

AU - Rei, Kinjo

AU - Vidović, Dragoslav

PY - 2014/11/7

Y1 - 2014/11/7

N2 - The synthesis, characterization and X-ray analysis of dichloro- and dibromo-borenium cations stabilized by a 4-membered carbene are reported. The ligand's structural changes, atypical for similar systems, were caused by coordination to electron deficient fragments and its CN2P ring strain.

AB - The synthesis, characterization and X-ray analysis of dichloro- and dibromo-borenium cations stabilized by a 4-membered carbene are reported. The ligand's structural changes, atypical for similar systems, were caused by coordination to electron deficient fragments and its CN2P ring strain.

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DO - 10.1039/c4dt01210k

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ER -

Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene: Electron deficiency compensation by asymmetric structural changes

Abstract

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ASJC Scopus Subject Areas

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