Distal difunctionalization of aldehydes via the triplet state of Breslow intermediates

Hongling Wang; Xingxing Wu; Yonggui Robin Chi

doi:10.1016/j.checat.2022.11.002

Distal difunctionalization of aldehydes via the triplet state of Breslow intermediates

Hongling Wang, Xingxing Wu^*, Yonggui Robin Chi^*

^*Corresponding author for this work

Research output: Contribution to journal › Comment/debate › peer-review

Abstract

In this issue of Chem Catalysis, Yan and co-workers describe a distal difunctionalization of aldehydes through a triplet state of deprotonated Breslow intermediates, involving an NHC-derived biradical species featuring unique reactivity that is formed upon excitation under thermal conditions resulting from the strikingly low singlet-triplet gap.

Original language	English
Pages (from-to)	3275-3277
Number of pages	3
Journal	Chem Catalysis
Volume	2
Issue number	12
DOIs	https://doi.org/10.1016/j.checat.2022.11.002
Publication status	Published - Dec 15 2022
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2022 Elsevier Inc.

ASJC Scopus Subject Areas

Chemistry (miscellaneous)
Physical and Theoretical Chemistry
Organic Chemistry

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10.1016/j.checat.2022.11.002

Cite this

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title = "Distal difunctionalization of aldehydes via the triplet state of Breslow intermediates",

abstract = "In this issue of Chem Catalysis, Yan and co-workers describe a distal difunctionalization of aldehydes through a triplet state of deprotonated Breslow intermediates, involving an NHC-derived biradical species featuring unique reactivity that is formed upon excitation under thermal conditions resulting from the strikingly low singlet-triplet gap.",

author = "Hongling Wang and Xingxing Wu and Chi, {Yonggui Robin}",

note = "Publisher Copyright: {\textcopyright} 2022 Elsevier Inc.",

year = "2022",

month = dec,

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doi = "10.1016/j.checat.2022.11.002",

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AU - Wu, Xingxing

AU - Chi, Yonggui Robin

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Y1 - 2022/12/15

N2 - In this issue of Chem Catalysis, Yan and co-workers describe a distal difunctionalization of aldehydes through a triplet state of deprotonated Breslow intermediates, involving an NHC-derived biradical species featuring unique reactivity that is formed upon excitation under thermal conditions resulting from the strikingly low singlet-triplet gap.

AB - In this issue of Chem Catalysis, Yan and co-workers describe a distal difunctionalization of aldehydes through a triplet state of deprotonated Breslow intermediates, involving an NHC-derived biradical species featuring unique reactivity that is formed upon excitation under thermal conditions resulting from the strikingly low singlet-triplet gap.

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DO - 10.1016/j.checat.2022.11.002

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JO - Chem Catalysis

JF - Chem Catalysis

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Distal difunctionalization of aldehydes via the triplet state of Breslow intermediates

Abstract

Bibliographical note

ASJC Scopus Subject Areas

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