Distillable ionic liquids: Reversible amide OAlkylation

Zheng Jian Chen; Hong Wei Xi; Kok Hwa Lim; Jong Min Lee

doi:10.1002/anie.201306476

Distillable ionic liquids: Reversible amide OAlkylation

Zheng Jian Chen, Hong Wei Xi, Kok Hwa Lim, Jong Min Lee^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

Put it in reverse: The recycling of ionic liquids (ILs) by distillation of the regenerated volatile precursors was demonstrated to be feasible by using low-cost amide-cation-derived aprotic ionic liquids prepared from reversible Oalkylation. The low viscosity (21.6cP at 25°C), high conductivity (15.45mS cm ^-1 at 25°C), and wide electrochemical windows (ca. 4.5V) of the ILs show potential for electrochemical applications.

Original language	English
Pages (from-to)	13392-13396
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	50
DOIs	https://doi.org/10.1002/anie.201306476
Publication status	Published - Dec 9 2013
Externally published	Yes

ASJC Scopus Subject Areas

Catalysis
General Chemistry

Keywords

alkylation
amides
computational chemistry
cyclic voltammetry
ionic liquids

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AU - Chen, Zheng Jian

AU - Xi, Hong Wei

AU - Lim, Kok Hwa

AU - Lee, Jong Min

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Y1 - 2013/12/9

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AB - Put it in reverse: The recycling of ionic liquids (ILs) by distillation of the regenerated volatile precursors was demonstrated to be feasible by using low-cost amide-cation-derived aprotic ionic liquids prepared from reversible Oalkylation. The low viscosity (21.6cP at 25°C), high conductivity (15.45mS cm -1 at 25°C), and wide electrochemical windows (ca. 4.5V) of the ILs show potential for electrochemical applications.

KW - alkylation

KW - amides

KW - computational chemistry

KW - cyclic voltammetry

KW - ionic liquids

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ER -

Distillable ionic liquids: Reversible amide OAlkylation

Abstract

ASJC Scopus Subject Areas

Keywords

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