Effect of A-site substitution of calcium on Zr-rich lead zirconate titanate

Haitao Huang; Zhang Tianshu; Joo Tien Oh; Peter Hing

doi:10.1080/00150190213960

Effect of A-site substitution of calcium on Zr-rich lead zirconate titanate

Haitao Huang^*, Zhang Tianshu, Joo Tien Oh, Peter Hing

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Effect of calcium substitution on the A-site of Zr-rich lead zirconate titanate Pb(Zr 0.94 Ti 0.06 )O 3 and Pb(Zr 0.92 Ti 0.08 )O 3 is studied. It is found that the rhombohedral structure of Zr-rich lead zirconate titanate changes to tetragonal and finally to cubic with increasing amount of calcium substitution. Both the dielectric constant and the Curie temperature decrease with the substitution of calcium on the A-site of the ABO 3 perovskite structure. A pyroelectric current peak is observed which is resulted from the phase transition from the low temperature rhombohedral ferroelectric phase F R ( LT ) to the high temperature F R ( HT ) one. Small amount of calcium substitution increases the peak value and also shifts the peak position to higher temperatures. However, further increase in the calcium content lowers the peak value and finally smears out the peak.

Original language	English
Pages (from-to)	55-65
Number of pages	11
Journal	Ferroelectrics
Volume	274
DOIs	https://doi.org/10.1080/00150190213960
Publication status	Published - Jan 1 2002
Externally published	Yes

ASJC Scopus Subject Areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics

Keywords

Dielectrics
Ferroelectrics
Pyroelectrics
PZT

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10.1080/00150190213960

Cite this

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title = "Effect of A-site substitution of calcium on Zr-rich lead zirconate titanate",

abstract = "Effect of calcium substitution on the A-site of Zr-rich lead zirconate titanate Pb(Zr 0.94 Ti 0.06 )O 3 and Pb(Zr 0.92 Ti 0.08 )O 3 is studied. It is found that the rhombohedral structure of Zr-rich lead zirconate titanate changes to tetragonal and finally to cubic with increasing amount of calcium substitution. Both the dielectric constant and the Curie temperature decrease with the substitution of calcium on the A-site of the ABO 3 perovskite structure. A pyroelectric current peak is observed which is resulted from the phase transition from the low temperature rhombohedral ferroelectric phase F R ( LT ) to the high temperature F R ( HT ) one. Small amount of calcium substitution increases the peak value and also shifts the peak position to higher temperatures. However, further increase in the calcium content lowers the peak value and finally smears out the peak.",

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author = "Haitao Huang and Zhang Tianshu and Oh, {Joo Tien} and Peter Hing",

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TY - JOUR

T1 - Effect of A-site substitution of calcium on Zr-rich lead zirconate titanate

AU - Huang, Haitao

AU - Tianshu, Zhang

AU - Oh, Joo Tien

AU - Hing, Peter

PY - 2002/1/1

Y1 - 2002/1/1

N2 - Effect of calcium substitution on the A-site of Zr-rich lead zirconate titanate Pb(Zr 0.94 Ti 0.06 )O 3 and Pb(Zr 0.92 Ti 0.08 )O 3 is studied. It is found that the rhombohedral structure of Zr-rich lead zirconate titanate changes to tetragonal and finally to cubic with increasing amount of calcium substitution. Both the dielectric constant and the Curie temperature decrease with the substitution of calcium on the A-site of the ABO 3 perovskite structure. A pyroelectric current peak is observed which is resulted from the phase transition from the low temperature rhombohedral ferroelectric phase F R ( LT ) to the high temperature F R ( HT ) one. Small amount of calcium substitution increases the peak value and also shifts the peak position to higher temperatures. However, further increase in the calcium content lowers the peak value and finally smears out the peak.

AB - Effect of calcium substitution on the A-site of Zr-rich lead zirconate titanate Pb(Zr 0.94 Ti 0.06 )O 3 and Pb(Zr 0.92 Ti 0.08 )O 3 is studied. It is found that the rhombohedral structure of Zr-rich lead zirconate titanate changes to tetragonal and finally to cubic with increasing amount of calcium substitution. Both the dielectric constant and the Curie temperature decrease with the substitution of calcium on the A-site of the ABO 3 perovskite structure. A pyroelectric current peak is observed which is resulted from the phase transition from the low temperature rhombohedral ferroelectric phase F R ( LT ) to the high temperature F R ( HT ) one. Small amount of calcium substitution increases the peak value and also shifts the peak position to higher temperatures. However, further increase in the calcium content lowers the peak value and finally smears out the peak.

KW - Dielectrics

KW - Ferroelectrics

KW - Pyroelectrics

KW - PZT

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JO - Ferroelectrics

JF - Ferroelectrics

ER -

Effect of A-site substitution of calcium on Zr-rich lead zirconate titanate

Abstract

ASJC Scopus Subject Areas

Keywords

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