Effect of oleic acid on the formation of lead zirconate titanate nanoplates

Yoko Takada; Ken ichi Mimura; Z. Liu; Kazumi Kato

doi:10.1016/j.jcrysgro.2020.125811

Effect of oleic acid on the formation of lead zirconate titanate nanoplates

Yoko Takada^*, Ken ichi Mimura, Z. Liu, Kazumi Kato

^*Corresponding author for this work

National Institute of Advanced Industrial Science and Technology

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Plate-shaped Pb(Zr,Ti)O₃ nanoparticles (PZT nanoplates) were synthesized by a hydrothermal method with oleic acid as a capping agent. With oleic acid, plate-shaped PZT nanoplates were obtained, whereas without oleic acid, large-sized PZT particles with rough surfaces were obtained. The sides of some PZT nanoplates synthesized with oleic acid had a unique step structure. The PZT nanoplates were characterized by various techniques. Fourier transform infrared spectroscopy revealed that the carboxylate group of oleic acid is chemically bound to the surface of PZT nanoplates. Selected area electron diffraction patterns revealed that these PZT nanoplates are single crystals and their normal axis corresponds to c-axis. These findings indicated that oleic acid played an important role in the formation of the uniquely shaped PZT particles.

Original language	English
Article number	125811
Journal	Journal of Crystal Growth
Volume	548
DOIs	https://doi.org/10.1016/j.jcrysgro.2020.125811
Publication status	Published - Oct 15 2020
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2020 Elsevier B.V.

ASJC Scopus Subject Areas

Condensed Matter Physics
Inorganic Chemistry
Materials Chemistry

Keywords

A1. Crystal morphology
A1. Nanostructures
B1. Inorganic compounds
B1. Nanomaterials
B1. Perovskites
B2. Piezoelectric materials

Access to Document

10.1016/j.jcrysgro.2020.125811

Cite this

@article{21bf08cc0d5c4bc4a7c8d7cbe0f1661a,

title = "Effect of oleic acid on the formation of lead zirconate titanate nanoplates",

abstract = "Plate-shaped Pb(Zr,Ti)O3 nanoparticles (PZT nanoplates) were synthesized by a hydrothermal method with oleic acid as a capping agent. With oleic acid, plate-shaped PZT nanoplates were obtained, whereas without oleic acid, large-sized PZT particles with rough surfaces were obtained. The sides of some PZT nanoplates synthesized with oleic acid had a unique step structure. The PZT nanoplates were characterized by various techniques. Fourier transform infrared spectroscopy revealed that the carboxylate group of oleic acid is chemically bound to the surface of PZT nanoplates. Selected area electron diffraction patterns revealed that these PZT nanoplates are single crystals and their normal axis corresponds to c-axis. These findings indicated that oleic acid played an important role in the formation of the uniquely shaped PZT particles.",

keywords = "A1. Crystal morphology, A1. Nanostructures, B1. Inorganic compounds, B1. Nanomaterials, B1. Perovskites, B2. Piezoelectric materials",

author = "Yoko Takada and Mimura, {Ken ichi} and Z. Liu and Kazumi Kato",

note = "Publisher Copyright: {\textcopyright} 2020 Elsevier B.V.",

year = "2020",

month = oct,

day = "15",

doi = "10.1016/j.jcrysgro.2020.125811",

language = "English",

volume = "548",

journal = "Journal of Crystal Growth",

issn = "0022-0248",

publisher = "Elsevier",

}

TY - JOUR

T1 - Effect of oleic acid on the formation of lead zirconate titanate nanoplates

AU - Takada, Yoko

AU - Mimura, Ken ichi

AU - Liu, Z.

AU - Kato, Kazumi

PY - 2020/10/15

Y1 - 2020/10/15

N2 - Plate-shaped Pb(Zr,Ti)O3 nanoparticles (PZT nanoplates) were synthesized by a hydrothermal method with oleic acid as a capping agent. With oleic acid, plate-shaped PZT nanoplates were obtained, whereas without oleic acid, large-sized PZT particles with rough surfaces were obtained. The sides of some PZT nanoplates synthesized with oleic acid had a unique step structure. The PZT nanoplates were characterized by various techniques. Fourier transform infrared spectroscopy revealed that the carboxylate group of oleic acid is chemically bound to the surface of PZT nanoplates. Selected area electron diffraction patterns revealed that these PZT nanoplates are single crystals and their normal axis corresponds to c-axis. These findings indicated that oleic acid played an important role in the formation of the uniquely shaped PZT particles.

AB - Plate-shaped Pb(Zr,Ti)O3 nanoparticles (PZT nanoplates) were synthesized by a hydrothermal method with oleic acid as a capping agent. With oleic acid, plate-shaped PZT nanoplates were obtained, whereas without oleic acid, large-sized PZT particles with rough surfaces were obtained. The sides of some PZT nanoplates synthesized with oleic acid had a unique step structure. The PZT nanoplates were characterized by various techniques. Fourier transform infrared spectroscopy revealed that the carboxylate group of oleic acid is chemically bound to the surface of PZT nanoplates. Selected area electron diffraction patterns revealed that these PZT nanoplates are single crystals and their normal axis corresponds to c-axis. These findings indicated that oleic acid played an important role in the formation of the uniquely shaped PZT particles.

KW - A1. Crystal morphology

KW - A1. Nanostructures

KW - B1. Inorganic compounds

KW - B1. Nanomaterials

KW - B1. Perovskites

KW - B2. Piezoelectric materials

UR - http://www.scopus.com/inward/record.url?scp=85089272555&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85089272555&partnerID=8YFLogxK

U2 - 10.1016/j.jcrysgro.2020.125811

DO - 10.1016/j.jcrysgro.2020.125811

M3 - Article

AN - SCOPUS:85089272555

SN - 0022-0248

VL - 548

JO - Journal of Crystal Growth

JF - Journal of Crystal Growth

M1 - 125811

ER -

Effect of oleic acid on the formation of lead zirconate titanate nanoplates

Abstract

Bibliographical note

ASJC Scopus Subject Areas

Keywords

Access to Document

Other files and links

Fingerprint

Cite this