Efficient copper-bisisoquinoline-based catalysts for selective aerobic oxidation of alcohols to aldehydes and ketones

Hao Yu Shen; Li Yan Ying; Hai Liang Jiang; Zaher M.A. Judeh

doi:10.3390/i8060505

Efficient copper-bisisoquinoline-based catalysts for selective aerobic oxidation of alcohols to aldehydes and ketones

Hao Yu Shen^*, Li Yan Ying, Hai Liang Jiang, Zaher M.A. Judeh

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

The selective oxidation of alcohols with molecular oxygen was efficiently completed in high conversion and selectivity using copper-bisisoquinoline-based catalysts under mild reaction condition. The effects of various parameters such as reaction temperature, reaction time, oxidant, ligands, etc, were studied. Solvent effect has been as well studied in ionic liquids [bmim]PF ₆, [omim]BF ₄ and [hmim]BF ₄, comparing to traditional volatile organic solvent. The use of ionic liquids was found to enhance the catalytic properties of the catalysts used.

Original language	English
Pages (from-to)	505-512
Number of pages	8
Journal	International Journal of Molecular Sciences
Volume	8
Issue number	6
DOIs	https://doi.org/10.3390/i8060505
Publication status	Published - Jun 2007
Externally published	Yes

ASJC Scopus Subject Areas

Catalysis
Molecular Biology
Spectroscopy
Computer Science Applications
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Keywords

Copper-bisisoquinoline-based catalysts
Ionic liquids
Selective oxidation of alcohols

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10.3390/i8060505

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title = "Efficient copper-bisisoquinoline-based catalysts for selective aerobic oxidation of alcohols to aldehydes and ketones",

abstract = "The selective oxidation of alcohols with molecular oxygen was efficiently completed in high conversion and selectivity using copper-bisisoquinoline-based catalysts under mild reaction condition. The effects of various parameters such as reaction temperature, reaction time, oxidant, ligands, etc, were studied. Solvent effect has been as well studied in ionic liquids [bmim]PF 6, [omim]BF 4 and [hmim]BF 4, comparing to traditional volatile organic solvent. The use of ionic liquids was found to enhance the catalytic properties of the catalysts used.",

keywords = "Copper-bisisoquinoline-based catalysts, Ionic liquids, Selective oxidation of alcohols",

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year = "2007",

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AU - Shen, Hao Yu

AU - Ying, Li Yan

AU - Jiang, Hai Liang

AU - Judeh, Zaher M.A.

PY - 2007/6

Y1 - 2007/6

N2 - The selective oxidation of alcohols with molecular oxygen was efficiently completed in high conversion and selectivity using copper-bisisoquinoline-based catalysts under mild reaction condition. The effects of various parameters such as reaction temperature, reaction time, oxidant, ligands, etc, were studied. Solvent effect has been as well studied in ionic liquids [bmim]PF 6, [omim]BF 4 and [hmim]BF 4, comparing to traditional volatile organic solvent. The use of ionic liquids was found to enhance the catalytic properties of the catalysts used.

AB - The selective oxidation of alcohols with molecular oxygen was efficiently completed in high conversion and selectivity using copper-bisisoquinoline-based catalysts under mild reaction condition. The effects of various parameters such as reaction temperature, reaction time, oxidant, ligands, etc, were studied. Solvent effect has been as well studied in ionic liquids [bmim]PF 6, [omim]BF 4 and [hmim]BF 4, comparing to traditional volatile organic solvent. The use of ionic liquids was found to enhance the catalytic properties of the catalysts used.

KW - Copper-bisisoquinoline-based catalysts

KW - Ionic liquids

KW - Selective oxidation of alcohols

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JO - International Journal of Molecular Sciences

JF - International Journal of Molecular Sciences

IS - 6

ER -

Efficient copper-bisisoquinoline-based catalysts for selective aerobic oxidation of alcohols to aldehydes and ketones

Abstract

ASJC Scopus Subject Areas

Keywords

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