Enantioselective allylation of aldehydes catalyzed by chiral indium(III) complexes immobilized in ionic liquids

Jun Lu; Shun Jun Ji; Teck Peng Loh

doi:10.1039/b500086f

Enantioselective allylation of aldehydes catalyzed by chiral indium(III) complexes immobilized in ionic liquids

Jun Lu^*, Shun Jun Ji, Teck Peng Loh

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

51 Citations (Scopus)

Abstract

In the presence of chiral catalytic complexes prepared from In(OTf) ₃ and chiral PYBOX ligands, allytributylstannane reacted with aldehydes in ionic liquids to afford the corresponding homoallylic alcohols in high enantioselectivities (86-94% ee) and good yields (68-89%); the chiral catalysts immobilized in ionic liquids could be reused with comparable enantioselectivities and yields.

Original language	English
Pages (from-to)	2345-2347
Number of pages	3
Journal	Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/b500086f
Publication status	Published - May 14 2005
Externally published	Yes

ASJC Scopus Subject Areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Enantioselective allylation of aldehydes catalyzed by chiral indium(III) complexes immobilized in ionic liquids",

abstract = "In the presence of chiral catalytic complexes prepared from In(OTf) 3 and chiral PYBOX ligands, allytributylstannane reacted with aldehydes in ionic liquids to afford the corresponding homoallylic alcohols in high enantioselectivities (86-94\% ee) and good yields (68-89\%); the chiral catalysts immobilized in ionic liquids could be reused with comparable enantioselectivities and yields.",

author = "Jun Lu and Ji, \{Shun Jun\} and Loh, \{Teck Peng\}",

year = "2005",

month = may,

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doi = "10.1039/b500086f",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Enantioselective allylation of aldehydes catalyzed by chiral indium(III) complexes immobilized in ionic liquids

AU - Lu, Jun

AU - Ji, Shun Jun

AU - Loh, Teck Peng

PY - 2005/5/14

Y1 - 2005/5/14

N2 - In the presence of chiral catalytic complexes prepared from In(OTf) 3 and chiral PYBOX ligands, allytributylstannane reacted with aldehydes in ionic liquids to afford the corresponding homoallylic alcohols in high enantioselectivities (86-94% ee) and good yields (68-89%); the chiral catalysts immobilized in ionic liquids could be reused with comparable enantioselectivities and yields.

AB - In the presence of chiral catalytic complexes prepared from In(OTf) 3 and chiral PYBOX ligands, allytributylstannane reacted with aldehydes in ionic liquids to afford the corresponding homoallylic alcohols in high enantioselectivities (86-94% ee) and good yields (68-89%); the chiral catalysts immobilized in ionic liquids could be reused with comparable enantioselectivities and yields.

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U2 - 10.1039/b500086f

DO - 10.1039/b500086f

M3 - Article

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EP - 2347

JO - Chemical Communications

JF - Chemical Communications

IS - 18

ER -

Enantioselective allylation of aldehydes catalyzed by chiral indium(III) complexes immobilized in ionic liquids

Abstract

ASJC Scopus Subject Areas

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