Enantioselective carbonyl-ene reactions of trifluoropyruvate in ionic liquid via a recyclable indium(III)-pybox complex

Jun Feng Zhao; Boon Hong Tan; Ming Kui Zhu; Teguh Budiono W. Tjan; Teck Peng Loh

doi:10.1002/adsc.201000170

Enantioselective carbonyl-ene reactions of trifluoropyruvate in ionic liquid via a recyclable indium(III)-pybox complex

Jun Feng Zhao, Boon Hong Tan, Ming Kui Zhu, Teguh Budiono W. Tjan, Teck Peng Loh

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

A highly enantioselective carbonyl-ene reaction of trifluoropyruvate catalyzed by a recyclable indium(III)-pybox complex in ionic liquid afforded trifluoromethyl-containing tertiary homoallylic alcohols with excellent yields (up to 98%) and enantioselectivities (up to 98% ee). Notably, this catalytic system can be recycled up to seven cycles.

Original language	English
Pages (from-to)	2085-2088
Number of pages	4
Journal	Advanced Synthesis and Catalysis
Volume	352
Issue number	11-12
DOIs	https://doi.org/10.1002/adsc.201000170
Publication status	Published - 2010
Externally published	Yes

ASJC Scopus Subject Areas

Catalysis
Organic Chemistry

Keywords

Asymmetric catalysis
Carbonyl-ene reaction
Indium
Ionic liquids

Access to Document

10.1002/adsc.201000170

Cite this

@article{c7248845ad2e4b52a88bd48063900082,

title = "Enantioselective carbonyl-ene reactions of trifluoropyruvate in ionic liquid via a recyclable indium(III)-pybox complex",

abstract = "A highly enantioselective carbonyl-ene reaction of trifluoropyruvate catalyzed by a recyclable indium(III)-pybox complex in ionic liquid afforded trifluoromethyl-containing tertiary homoallylic alcohols with excellent yields (up to 98%) and enantioselectivities (up to 98% ee). Notably, this catalytic system can be recycled up to seven cycles.",

keywords = "Asymmetric catalysis, Carbonyl-ene reaction, Indium, Ionic liquids",

author = "Zhao, {Jun Feng} and Tan, {Boon Hong} and Zhu, {Ming Kui} and Tjan, {Teguh Budiono W.} and Loh, {Teck Peng}",

year = "2010",

doi = "10.1002/adsc.201000170",

language = "English",

volume = "352",

pages = "2085--2088",

journal = "Advanced Synthesis and Catalysis",

issn = "1615-4150",

publisher = "Wiley-VCH Verlag",

number = "11-12",

}

TY - JOUR

T1 - Enantioselective carbonyl-ene reactions of trifluoropyruvate in ionic liquid via a recyclable indium(III)-pybox complex

AU - Zhao, Jun Feng

AU - Tan, Boon Hong

AU - Zhu, Ming Kui

AU - Tjan, Teguh Budiono W.

AU - Loh, Teck Peng

PY - 2010

Y1 - 2010

N2 - A highly enantioselective carbonyl-ene reaction of trifluoropyruvate catalyzed by a recyclable indium(III)-pybox complex in ionic liquid afforded trifluoromethyl-containing tertiary homoallylic alcohols with excellent yields (up to 98%) and enantioselectivities (up to 98% ee). Notably, this catalytic system can be recycled up to seven cycles.

AB - A highly enantioselective carbonyl-ene reaction of trifluoropyruvate catalyzed by a recyclable indium(III)-pybox complex in ionic liquid afforded trifluoromethyl-containing tertiary homoallylic alcohols with excellent yields (up to 98%) and enantioselectivities (up to 98% ee). Notably, this catalytic system can be recycled up to seven cycles.

KW - Asymmetric catalysis

KW - Carbonyl-ene reaction

KW - Indium

KW - Ionic liquids

UR - http://www.scopus.com/inward/record.url?scp=77956354236&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=77956354236&partnerID=8YFLogxK

U2 - 10.1002/adsc.201000170

DO - 10.1002/adsc.201000170

M3 - Article

AN - SCOPUS:77956354236

SN - 1615-4150

VL - 352

SP - 2085

EP - 2088

JO - Advanced Synthesis and Catalysis

JF - Advanced Synthesis and Catalysis

IS - 11-12

ER -

Enantioselective carbonyl-ene reactions of trifluoropyruvate in ionic liquid via a recyclable indium(III)-pybox complex

Abstract

ASJC Scopus Subject Areas

Keywords

Access to Document

Other files and links

Fingerprint

Cite this