Enantioselective epoxidation of α,β-enones promoted by (1R,3S,4S)-2-azanorbornyl-3-methanol as an organocatalyst

Jun Lu; Yun He Xu; Feng Liu; Teck Peng Loh

doi:10.1016/j.tetlet.2008.07.175

Enantioselective epoxidation of α,β-enones promoted by (1R,3S,4S)-2-azanorbornyl-3-methanol as an organocatalyst

Jun Lu, Yun He Xu, Feng Liu, Teck Peng Loh^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

(1R,3S,4S)-2-Azanorbornyl-3-methanol was synthesized form (R)-1-phenylethylamine and used as a catalyst for the enantioselective epoxidation of α,β-enones to afford the corresponding epoxides in good yields and high enantioselectivities at room temperature.

Original language	English
Pages (from-to)	6007-6008
Number of pages	2
Journal	Tetrahedron Letters
Volume	49
Issue number	41
DOIs	https://doi.org/10.1016/j.tetlet.2008.07.175
Publication status	Published - Oct 6 2008
Externally published	Yes

ASJC Scopus Subject Areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2008.07.175

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title = "Enantioselective epoxidation of α,β-enones promoted by (1R,3S,4S)-2-azanorbornyl-3-methanol as an organocatalyst",

abstract = "(1R,3S,4S)-2-Azanorbornyl-3-methanol was synthesized form (R)-1-phenylethylamine and used as a catalyst for the enantioselective epoxidation of α,β-enones to afford the corresponding epoxides in good yields and high enantioselectivities at room temperature.",

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AU - Lu, Jun

AU - Xu, Yun He

AU - Liu, Feng

AU - Loh, Teck Peng

PY - 2008/10/6

Y1 - 2008/10/6

N2 - (1R,3S,4S)-2-Azanorbornyl-3-methanol was synthesized form (R)-1-phenylethylamine and used as a catalyst for the enantioselective epoxidation of α,β-enones to afford the corresponding epoxides in good yields and high enantioselectivities at room temperature.

AB - (1R,3S,4S)-2-Azanorbornyl-3-methanol was synthesized form (R)-1-phenylethylamine and used as a catalyst for the enantioselective epoxidation of α,β-enones to afford the corresponding epoxides in good yields and high enantioselectivities at room temperature.

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DO - 10.1016/j.tetlet.2008.07.175

M3 - Article

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SN - 0040-4039

VL - 49

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

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ER -

Enantioselective epoxidation of α,β-enones promoted by (1R,3S,4S)-2-azanorbornyl-3-methanol as an organocatalyst

Abstract

ASJC Scopus Subject Areas

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