TY - JOUR
T1 - Gel permeation chromatographic determination of activation rate constants in nitroxide-controlled free radical polymerization, 2
T2 - Analysis of evolution of polydispersities
AU - Fukuda, Takeshi
AU - Goto, Atsushi
PY - 1997/8
Y1 - 1997/8
N2 - The dissociation rate constant kd of the PS-TEMPO adduct, where PS is polystyrene and TEMPO is 2,2,6,6-tetramethylpiperidin-1-oxyl, was determined by the gel permeation chromatographic tracing of the evolution of polydispersities at an early stage of styrene polymerization with a model PS-TEMPO adduct as initiator. The results agree with those obtained by the direct method in Part 1.
AB - The dissociation rate constant kd of the PS-TEMPO adduct, where PS is polystyrene and TEMPO is 2,2,6,6-tetramethylpiperidin-1-oxyl, was determined by the gel permeation chromatographic tracing of the evolution of polydispersities at an early stage of styrene polymerization with a model PS-TEMPO adduct as initiator. The results agree with those obtained by the direct method in Part 1.
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U2 - 10.1002/marc.1997.030180809
DO - 10.1002/marc.1997.030180809
M3 - Article
AN - SCOPUS:0031507219
SN - 1022-1336
VL - 18
SP - 683
EP - 688
JO - Macromolecular Rapid Communications
JF - Macromolecular Rapid Communications
IS - 8
ER -