Generation of β-keto radicals from cyclopropanols catalyzed by AgNO3

Shunsuke Chiba; Zhengyan Cao; Serry Atta Atta El Bialy; Koichi Narasaka

doi:10.1246/cl.2006.18

Generation of β-keto radicals from cyclopropanols catalyzed by AgNO₃

Shunsuke Chiba, Zhengyan Cao, Serry Atta Atta El Bialy, Koichi Narasaka^*

^*Corresponding author for this work

The University of Tokyo

Research output: Contribution to journal › Article › peer-review

72 Citations (Scopus)

Abstract

Various β-keto radicals are generated from cyclopropanols by treatment with a catalytic amount of AgNO₃ and (NH₄) ₂S₂O₈ as a reoxidant in the presence of pyridine. Thus, generated β-keto radicals react with alkenes to yield addition products.

Original language	English
Pages (from-to)	18-19
Number of pages	2
Journal	Chemistry Letters
Volume	35
Issue number	1
DOIs	https://doi.org/10.1246/cl.2006.18
Publication status	Published - Jan 5 2006
Externally published	Yes

ASJC Scopus Subject Areas

General Chemistry

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title = "Generation of β-keto radicals from cyclopropanols catalyzed by AgNO3",

abstract = "Various β-keto radicals are generated from cyclopropanols by treatment with a catalytic amount of AgNO3 and (NH4) 2S2O8 as a reoxidant in the presence of pyridine. Thus, generated β-keto radicals react with alkenes to yield addition products.",

author = "Shunsuke Chiba and Zhengyan Cao and {El Bialy}, {Serry Atta Atta} and Koichi Narasaka",

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AU - Chiba, Shunsuke

AU - Cao, Zhengyan

AU - El Bialy, Serry Atta Atta

AU - Narasaka, Koichi

PY - 2006/1/5

Y1 - 2006/1/5

N2 - Various β-keto radicals are generated from cyclopropanols by treatment with a catalytic amount of AgNO3 and (NH4) 2S2O8 as a reoxidant in the presence of pyridine. Thus, generated β-keto radicals react with alkenes to yield addition products.

AB - Various β-keto radicals are generated from cyclopropanols by treatment with a catalytic amount of AgNO3 and (NH4) 2S2O8 as a reoxidant in the presence of pyridine. Thus, generated β-keto radicals react with alkenes to yield addition products.

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DO - 10.1246/cl.2006.18

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JO - Chemistry Letters

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ER -

Generation of β-keto radicals from cyclopropanols catalyzed by AgNO₃

Abstract

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