Germylone-bridged bimetallic Ir and Rh complexes

Bochao Su; Kei Ota; Yongxin Li; Rei Kinjo

doi:10.1039/c9dt00145j

Germylone-bridged bimetallic Ir and Rh complexes

Bochao Su, Kei Ota, Yongxin Li, Rei Kinjo^*

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The reactions of germylone 1 with one equivalent of [M(COD)Cl]₂ (M = Ir, Rh) afforded the germylone-bridged bimetallic complexes 2 and 3, which have been spectroscopically and structurally characterized. Density functional theory (DFT) studies reveal the relatively strong interactions between the Ge atom and these metals. By the reaction of [Rh(COD)Cl]₂ with CO followed by addition of 1, a complex 4 involving a Rh-Ge-Rh-Ge-Rh chain was also synthesized.

Original language	English
Pages (from-to)	3555-3559
Number of pages	5
Journal	Dalton Transactions
Volume	48
Issue number	11
DOIs	https://doi.org/10.1039/c9dt00145j
Publication status	Published - 2019
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2019 The Royal Society of Chemistry.

ASJC Scopus Subject Areas

Inorganic Chemistry

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title = "Germylone-bridged bimetallic Ir and Rh complexes",

abstract = "The reactions of germylone 1 with one equivalent of [M(COD)Cl]2 (M = Ir, Rh) afforded the germylone-bridged bimetallic complexes 2 and 3, which have been spectroscopically and structurally characterized. Density functional theory (DFT) studies reveal the relatively strong interactions between the Ge atom and these metals. By the reaction of [Rh(COD)Cl]2 with CO followed by addition of 1, a complex 4 involving a Rh-Ge-Rh-Ge-Rh chain was also synthesized.",

author = "Bochao Su and Kei Ota and Yongxin Li and Rei Kinjo",

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T1 - Germylone-bridged bimetallic Ir and Rh complexes

AU - Su, Bochao

AU - Ota, Kei

AU - Li, Yongxin

AU - Kinjo, Rei

PY - 2019

Y1 - 2019

N2 - The reactions of germylone 1 with one equivalent of [M(COD)Cl]2 (M = Ir, Rh) afforded the germylone-bridged bimetallic complexes 2 and 3, which have been spectroscopically and structurally characterized. Density functional theory (DFT) studies reveal the relatively strong interactions between the Ge atom and these metals. By the reaction of [Rh(COD)Cl]2 with CO followed by addition of 1, a complex 4 involving a Rh-Ge-Rh-Ge-Rh chain was also synthesized.

AB - The reactions of germylone 1 with one equivalent of [M(COD)Cl]2 (M = Ir, Rh) afforded the germylone-bridged bimetallic complexes 2 and 3, which have been spectroscopically and structurally characterized. Density functional theory (DFT) studies reveal the relatively strong interactions between the Ge atom and these metals. By the reaction of [Rh(COD)Cl]2 with CO followed by addition of 1, a complex 4 involving a Rh-Ge-Rh-Ge-Rh chain was also synthesized.

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Germylone-bridged bimetallic Ir and Rh complexes

Abstract

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