Heterobimetallic ruthenium-cobalt complexes containing the pentamethylcyclopentadienyl or indenyl ligand

Sin Yee Ng; Lai Yoong Goh; Lip Lin Koh; Weng Kee Leong; Geok Kheng Tan; Suming Ye; Yinghuai Zhu

doi:10.1002/ejic.200500785

Heterobimetallic ruthenium-cobalt complexes containing the pentamethylcyclopentadienyl or indenyl ligand

Sin Yee Ng, Lai Yoong Goh^*, Lip Lin Koh, Weng Kee Leong, Geok Kheng Tan, Suming Ye, Yinghuai Zhu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The salt elimination reaction between NaCo(CO)₄ and the ruthenium complexes LRu(diphos)Cl and [(Ind)Ru(CO)₂Cl] afforded the Ru-Co bimetallic complexes [LRu(μ-CO)₂(μ-diphos)Co(CO) ₂] [L = C₅Me₅ (Cp*), diphos = Ph ₂P(CH₂)_nPPh₂, 3a: n = 1 , or 3b: n = 2; 3. L = C₉H₇ (Ind), diphos = Ph₂PCH ₂PPh₂ ] and [(Ind)Ru(CO)₂Co(CO)₄] (3d), respectively, in high yields. However, the same reaction with the monophosphane analogue, [(Ind)Ru(PPh₃)₂Cl], gave the heterobimetallic complex [(Ind)Ru(PPh₃)(CO)(μ-CO)Co(CO) ₃] (3e) in fair yield, together with redox-initiated derivatives Ru(PPh₃)₂(CO)₃ (4e) and [(Ind)Co(CO)(PPh ₃)] (6e). A similar redox process in the reaction of the dppf analogue, [(Ind) Ru(dppf)Cl] (dppf = 1,1′-diphenylphosphanylferrocene) gave [Ru(dppf)(CO)₃] (4f) and [(Ind)Co(CO)₂] (6f), together with a complex salt [(Ind)Ru(dppf)(CO)][Co(CO₄)] [5f·Co(CO)₄].

Original language	English
Pages (from-to)	663-670
Number of pages	8
Journal	European Journal of Inorganic Chemistry
Issue number	3
DOIs	https://doi.org/10.1002/ejic.200500785
Publication status	Published - Feb 6 2006
Externally published	Yes

ASJC Scopus Subject Areas

Inorganic Chemistry

Keywords

Cobalt
Heterometallic complexes
Indenyl
Phosphanes
Ruthenium

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@article{f818544b6cd84eb59d7a5b35b7a21dbd,

title = "Heterobimetallic ruthenium-cobalt complexes containing the pentamethylcyclopentadienyl or indenyl ligand",

abstract = "The salt elimination reaction between NaCo(CO)4 and the ruthenium complexes LRu(diphos)Cl and [(Ind)Ru(CO)2Cl] afforded the Ru-Co bimetallic complexes [LRu(μ-CO)2(μ-diphos)Co(CO) 2] [L = C5Me5 (Cp*), diphos = Ph 2P(CH2)nPPh2, 3a: n = 1 , or 3b: n = 2; 3. L = C9H7 (Ind), diphos = Ph2PCH 2PPh2 ] and [(Ind)Ru(CO)2Co(CO)4] (3d), respectively, in high yields. However, the same reaction with the monophosphane analogue, [(Ind)Ru(PPh3)2Cl], gave the heterobimetallic complex [(Ind)Ru(PPh3)(CO)(μ-CO)Co(CO) 3] (3e) in fair yield, together with redox-initiated derivatives Ru(PPh3)2(CO)3 (4e) and [(Ind)Co(CO)(PPh 3)] (6e). A similar redox process in the reaction of the dppf analogue, [(Ind) Ru(dppf)Cl] (dppf = 1,1′-diphenylphosphanylferrocene) gave [Ru(dppf)(CO)3] (4f) and [(Ind)Co(CO)2] (6f), together with a complex salt [(Ind)Ru(dppf)(CO)][Co(CO4)] [5f·Co(CO)4].",

keywords = "Cobalt, Heterometallic complexes, Indenyl, Phosphanes, Ruthenium",

author = "Ng, {Sin Yee} and Goh, {Lai Yoong} and Koh, {Lip Lin} and Leong, {Weng Kee} and Tan, {Geok Kheng} and Suming Ye and Yinghuai Zhu",

year = "2006",

month = feb,

day = "6",

doi = "10.1002/ejic.200500785",

language = "English",

pages = "663--670",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "3",

}

TY - JOUR

T1 - Heterobimetallic ruthenium-cobalt complexes containing the pentamethylcyclopentadienyl or indenyl ligand

AU - Ng, Sin Yee

AU - Goh, Lai Yoong

AU - Koh, Lip Lin

AU - Leong, Weng Kee

AU - Tan, Geok Kheng

AU - Ye, Suming

AU - Zhu, Yinghuai

PY - 2006/2/6

Y1 - 2006/2/6

N2 - The salt elimination reaction between NaCo(CO)4 and the ruthenium complexes LRu(diphos)Cl and [(Ind)Ru(CO)2Cl] afforded the Ru-Co bimetallic complexes [LRu(μ-CO)2(μ-diphos)Co(CO) 2] [L = C5Me5 (Cp*), diphos = Ph 2P(CH2)nPPh2, 3a: n = 1 , or 3b: n = 2; 3. L = C9H7 (Ind), diphos = Ph2PCH 2PPh2 ] and [(Ind)Ru(CO)2Co(CO)4] (3d), respectively, in high yields. However, the same reaction with the monophosphane analogue, [(Ind)Ru(PPh3)2Cl], gave the heterobimetallic complex [(Ind)Ru(PPh3)(CO)(μ-CO)Co(CO) 3] (3e) in fair yield, together with redox-initiated derivatives Ru(PPh3)2(CO)3 (4e) and [(Ind)Co(CO)(PPh 3)] (6e). A similar redox process in the reaction of the dppf analogue, [(Ind) Ru(dppf)Cl] (dppf = 1,1′-diphenylphosphanylferrocene) gave [Ru(dppf)(CO)3] (4f) and [(Ind)Co(CO)2] (6f), together with a complex salt [(Ind)Ru(dppf)(CO)][Co(CO4)] [5f·Co(CO)4].

AB - The salt elimination reaction between NaCo(CO)4 and the ruthenium complexes LRu(diphos)Cl and [(Ind)Ru(CO)2Cl] afforded the Ru-Co bimetallic complexes [LRu(μ-CO)2(μ-diphos)Co(CO) 2] [L = C5Me5 (Cp*), diphos = Ph 2P(CH2)nPPh2, 3a: n = 1 , or 3b: n = 2; 3. L = C9H7 (Ind), diphos = Ph2PCH 2PPh2 ] and [(Ind)Ru(CO)2Co(CO)4] (3d), respectively, in high yields. However, the same reaction with the monophosphane analogue, [(Ind)Ru(PPh3)2Cl], gave the heterobimetallic complex [(Ind)Ru(PPh3)(CO)(μ-CO)Co(CO) 3] (3e) in fair yield, together with redox-initiated derivatives Ru(PPh3)2(CO)3 (4e) and [(Ind)Co(CO)(PPh 3)] (6e). A similar redox process in the reaction of the dppf analogue, [(Ind) Ru(dppf)Cl] (dppf = 1,1′-diphenylphosphanylferrocene) gave [Ru(dppf)(CO)3] (4f) and [(Ind)Co(CO)2] (6f), together with a complex salt [(Ind)Ru(dppf)(CO)][Co(CO4)] [5f·Co(CO)4].

KW - Cobalt

KW - Heterometallic complexes

KW - Indenyl

KW - Phosphanes

KW - Ruthenium

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U2 - 10.1002/ejic.200500785

DO - 10.1002/ejic.200500785

M3 - Article

AN - SCOPUS:32644435062

SN - 1434-1948

SP - 663

EP - 670

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 3

ER -

Heterobimetallic ruthenium-cobalt complexes containing the pentamethylcyclopentadienyl or indenyl ligand

Abstract

ASJC Scopus Subject Areas

Keywords

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