High-temperature phase transitions, dielectric relaxation, and ionic mobility of proustite, Ag3AsS3, and pyrargyrite, Ag3SbS3

Kristin A. Schönau; Simon A.T. Redfern

doi:10.1063/1.1520720

High-temperature phase transitions, dielectric relaxation, and ionic mobility of proustite, Ag₃AsS₃, and pyrargyrite, Ag₃SbS₃

Kristin A. Schönau, Simon A.T. Redfern^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

The nature of high-temperature phase transitions in natural and synthetic proustite, Ag₃AsS₃ was studied and compared with its natural counterpart pyrargyrite, Ag₃SbS₃. It was shown that the high-temperature behavior of proustite was characterized by silver ion mobility within the structure. The X-ray and neutron powder diffraction technique, dielectric spectroscopy, and dynamic mechanical analysis were used to investigate proustite and pyrargyrite structures, as a function of temperature.

Original language	English
Pages (from-to)	7415-7424
Number of pages	10
Journal	Journal of Applied Physics
Volume	92
Issue number	12
DOIs	https://doi.org/10.1063/1.1520720
Publication status	Published - Dec 15 2002
Externally published	Yes

ASJC Scopus Subject Areas

General Physics and Astronomy

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AB - The nature of high-temperature phase transitions in natural and synthetic proustite, Ag3AsS3 was studied and compared with its natural counterpart pyrargyrite, Ag3SbS3. It was shown that the high-temperature behavior of proustite was characterized by silver ion mobility within the structure. The X-ray and neutron powder diffraction technique, dielectric spectroscopy, and dynamic mechanical analysis were used to investigate proustite and pyrargyrite structures, as a function of temperature.

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High-temperature phase transitions, dielectric relaxation, and ionic mobility of proustite, Ag₃AsS₃, and pyrargyrite, Ag₃SbS₃

Abstract

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